Cinética de sorción de NO3- en esmectita-illita
Resumen
En el presente trabajo de investigación se evaluó la cinética de sorción de nitratos a temperatura ambiente en soluciones acuosas de NaNO3 con concentraciones de NO3- de 25, 50, 100 y 200 mg/L con valores de pH 6, 7 y 8, empleando esmectita-illita purificada proveniente de una toba riolítica ubicada en el municipio de Epazoyucan, Hidalgo, con una abundancia relativa de esmectita 36.52%, illita 8.69%, cuarzo 39.13% y plagioclasa sódica 15.65%, sin considerar las fases amorfas o minoritarias no detectadas por difracción de rayos X. Las curvas cinéticas determinadas experimentalmente indican una mayor sorción de NO3- en las soluciones de mayor concentración (200 mg/L de NO3-), particularmente a valores de pH 7, siendo la cantidad máxima retenida de NO3- de 0.0903 meq/g (5.5995 mg/g). Aunque se emplearon los modelos cinéticos de pseudo primer orden y de pseudo segundo orden, se considera que la cinética de pseudo segundo orden presenta una mejor correlación con los datos experimentales.
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Derechos de autor 2023 Misael Cruz-Sánchez, Cynthia Becerril-Enciso, Jorge Alcaraz-Cienfuegos, María Patricia Girón-García, Carlos Esquivel-Macías
Esta obra está bajo licencia internacional Creative Commons Reconocimiento-NoComercial-SinObrasDerivadas 4.0.
