Desarrollo de películas adsorbentes y fotocatalíticas de TiO2-acetato de celulosa

Palabras clave: Acetato de celulosa, Adsorción, Anatasa, Fotocatálisis, Cinética, Óxido de titanio, Remoción

Resumen

El objetivo de este trabajo fue la obtención de un material de óxido de titanio-acetato de celulosa (TiO2-AC) en forma de película, con propiedades adsorbentes y fotocatalíticas. Se utilizó azul de metileno (AM) como modelo en las pruebas de adsorción y fotocatálisis bajo irradiación solar. Los resultados de la caracterización morfológica y óptica de las muestras indican que se obtuvieron películas blancas, flexibles y porosas, con un band gap de 3.15 eV. Los resultados de la caracterización química y estructural indican que la película es un composito TiO2-AC, resultando de la interacción entre los grupos acetil del polímero y el grupo tinalol del TiO2. Los resultados de la evaluación de las nanopartículas de TiO2 y de la película TiO2-AC indican que la adsorción de AM es bien modelada por la isoterma de Langmuir. Los valores de las constantes de velocidad de remoción de AM son mayores en un orden de magnitud que los valores de las constantes de velocidad de fotodegradación, debido a la funcionalidad dual adsorbente/fotocatalizador de ambas muestras.

Descargas

La descarga de datos todavía no está disponible.

Citas

Abram, A., & Drazic, G. (2021). Structural properties of hydrothermally-prepared boehmite/TiO2 coatings. Open Ceramics, 7, 100153. https://doi.org/https://doi.org/10.1016/j.oceram.2021.100153

Akkaya Arıer, Ü. Ö. (2016). Optical and structural properties of sol-gel derived brookite TiO2-SiO2 nano-composite films with different SiO2:TiO2 ratios. Optik - International Journal for Light and Electron Optics, 127(16), 6439–6445. https://doi.org/http://dx.doi.org/10.1016/j.ijleo.2016.04.038

Ali, I., Suhail, M., Alothman, Z. A., & Alwarthan, A. (2018). Recent advances in syntheses, properties and applications of TiO2 nanostructures. RSC Advances, 8(53), 30125–30147. https://doi.org/10.1039/c8ra06517a

Candido, R. G., Godoy, G. G., & Gonc, A. R. (2017). Characterization and application of cellulose acetate synthesized from sugarcane bagasse. Carbohydrate Polymers, 167, 280–289.

Davari, N., Falletta, E., Bianchi, C. L., Yargeau, V., & Boffito, D. C. (2024). TiO2 nanotubes immobilized on polyurethane foam as a floating photocatalyst for water treatment. Catalysis Today, 436(October 2023), 114725. https://doi.org/10.1016/j.cattod.2024.114725

De Campos, E. A., De Campos, S. D., Roos, A. A., De Souza, B. V. C., Schneider, J. M., Uliana, M. B., & De Oliveira, R. C. (2013). Titanium dioxide dispersed on cellulose acetate and its application in methylene blue photodegradation. Polymers and Polymer Composites, 21(7), 423–430. https://doi.org/10.1177/096739111302100703

Elmaghraby, N. A., Omer, A. M., Kenawy, E. R., Gaber, M., Hassaan, M. A., Ragab, S., Hossain, I., & Nemr, A. El. (2023). Electrospun cellulose acetate/activated carbon composite modified by EDTA (rC/AC‑EDTA ) for efficient methylene blue dye removal. Scientific Reports, 13, 1–16. https://doi.org/10.1038/s41598-023-36994-5

Estrada-Flores, S., Martínez-Luévanos, A., Perez-Berumen, C. M., García-Cerda, L. A., & Flores-Guia, T. E. (2020). Relationship between morphology, porosity, and the photocatalytic activity of TiO2 obtained by sol–gel method assisted with ionic and nonionic surfactants. Boletin de La Sociedad Espanola de Ceramica y Vidrio, 59(5), 209–218. https://doi.org/10.1016/j.bsecv.2019.10.003

Ezzat, D., Youssif, M., Elhaes, H., & El-Nahass, M. (2024). XRD and UV–Vis studies of cellulose acetate film blended with different concentrations of nano-metal oxide. Optical and Quantum Electronics, 56(5), 1–21. https://doi.org/10.1007/s11082-024-06480-x

Gaminian, H., & Montazer, M. (2018). Carbon black enhanced conductivity, carbon yield and dye adsorption of sustainable cellulose derived carbon nanofibers. Cellulose, 25(9), 5227–5240. https://doi.org/10.1007/s10570-018-1929-6

Hokkanen, S., Bhatnagar, A., & Sillanpää, M. (2016). A review on modification methods to cellulose-based adsorbents to improve adsorption capacity. Water Research, 91, 156–173. https://doi.org/10.1016/j.watres.2016.01.008

Jaramillo-Fierro, X., & Cuenca, G. (2024). Enhancing Methylene Blue Removal through Adsorption and Photocatalysis—A Study on the GO/ZnTiO3/TiO2 Composite. International Journal of Molecular Sciences, 25(8), 1–27. https://doi.org/10.3390/ijms25084367

Jin, X., Xu, J., Wang, X., Xie, Z., Liu, Z., Liang, B., Chen, D., & Shen, G. (2014). Flexible TiO2/cellulose acetate hybrid film as a recyclable photocatalyst. RSC Advances, 4(25), 12640–12648. https://doi.org/10.1039/c3ra47710j

Joshy, D., Narendranath, S. B., Ismail, Y. A., & Periyat, P. (2022). Recent progress in one dimensional TiO2 nanomaterials as photoanodes in dye-sensitized solar cells. Nanoscale Advances, 73, 5202–5232. https://doi.org/10.1039/d2na00437b

Kaiblinger, N., Hahn, R., Beck, J., Wang, Y., & Carta, G. (2024). Direct calculation of the equilibrium composition for multi-component Langmuir isotherms in batch adsorption. Adsorption, 30(1), 51–56. https://doi.org/10.1007/s10450-023-00429-4

Maria Ulfa, Hafid Al Afif, Teguh Endah Saraswati, and H. B. (2022). Fast Removal of Methylene Blue via Adsorption-Photodegradation. Materials, 15, 5471.

Marinho, B. A., Cristóvão, R. O., Djellabi, R., Loureiro, J. M., Boaventura, R. A. R., & Vilar, V. J. P. (2017). Photocatalytic reduction of Cr (VI) over TiO2 -coated cellulose acetate monolithic structures using solar light. Applied Catalysis B: Environmental, 203, 18–30.

Palliyalil, S., Chola, R. K. V., Vigneshwaran, S., Poovathumkuzhi, N. C., Chelaveettil, B. M., & Meenakshi, S. (2022). Ternary system of TiO2 confined chitosan–polyaniline heterostructure photocatalyst for the degradation of anionic and cationic dyes. Environmental Technology and Innovation, 28, 102586. https://doi.org/10.1016/j.eti.2022.102586

Pandele, A. M., Comanici, F. E., Carp, C. A., Miculescu, F., Voicu, S. I., Thakur, V. K., & Serban, B. C. (2017). Synthesis and characterization of cellulose acetate-hydroxyapatite micro and nano composites membranes for water purification and biomedical applications. Vacuum, 146, 599–605.

Rajesha, B. J., Vishaka, V. H., Balakrishna, G. R., Padaki, M., & Nazri, N. A. M. (2017). Effective composite membranes of cellulose acetate for removal of benzophenone-3. Journal of Water Process Engineering. https://doi.org/10.1016/j.jwpe.2017.06.003

Santos-Sauceda, I., Castillo-Ortega, M. M., del Castillo-Castro, T., Armenta-Villegas, L., & Ramírez-Bon, R. (2021). Electrospun cellulose acetate fibers for the photodecolorization of methylene blue solutions under natural sunlight. Polymer Bulletin, 78(8), 4419–4438. https://doi.org/10.1007/s00289-020-03324-y

Sharma, D., Kumari, M., & Dhayal, V. (2021). Fabrication and characterization of cellulose/pva/TiO2 nanocomposite thin film as a photocatalyst. Materials Today: Proceedings, 43, 2970–2974. https://doi.org/10.1016/j.matpr.2021.01.323

Srivastava, S. K. (2024). Recent advances in removal of pharmaceutical pollutants in wastewater using metal oxides and carbonaceous materials as photocatalysts: a review. RSC Applied Interfaces, 1(3), 340–429. https://doi.org/10.1039/d3lf00142c

Tian, X., Cui, X., Lai, T., Ren, J., Yang, Z., Xiao, M., Wang, B., Xiao, X., & Wang, Y. (2021). Gas sensors based on TiO2 nanostructured materials for the detection of hazardous gases: A review. Nano Materials Science, 3(4), 390–403. https://doi.org/10.1016/j.nanoms.2021.05.011

Wang, S. D., Ma, Q., Liu, H., Wang, K., Ling, L. Z., & Zhang, K. Q. (2015). Robust electrospinning cellulose acetate@TiO2 ultrafine fibers for dyeing water treatment by photocatalytic reactions. RSC Advances, 5(51), 40521–40530. https://doi.org/10.1039/c5ra03797b

ZabihiSahebi, A., Koushkbaghi, S., Pishnamazi, M., Askari, A., Khosravi, R., & Irani, M. (2019). Synthesis of cellulose acetate/chitosan/SWCNT/Fe3O4/TiO2 composite nanofibers for the removal of Cr(VI), As(V), Methylene blue and Congo red from aqueous solutions. International Journal of Biological Macromolecules, 140, 1296–1304. https://doi.org/10.1016/j.ijbiomac.2019.08.214

Zakria, H. S., Othman, M. H. D., Kamaludin, R., Sheikh Abdul Kadir, S. H., Kurniawan, T. A., & Jilani, A. (2021). Immobilization techniques of a photocatalyst into and onto a polymer membrane for photocatalytic activity. RSC Advances, 11(12), 6985–7014. https://doi.org/10.1039/d0ra10964a

Publicado
2024-10-05
Cómo citar
Estrada Flores, S., Herrera Pérez, M. F., Avalos Cárdenas, M., Martínez-Luévanos, A., & Aguilera González, E. N. (2024). Desarrollo de películas adsorbentes y fotocatalíticas de TiO2-acetato de celulosa. Tópicos De Investigación En Ciencias De La Tierra Y Materiales, 11(11), 110-117. https://doi.org/10.29057/aactm.v11i11.13384