Adsorción de Verde Malaquita Utilizando Magnetita: Estudio Cinético y Termodinámico

Autores/as

DOI:

https://doi.org/10.29057/aactm.v12i12.15261

Palabras clave:

Verde Malaquita, Adsorción, Magnetita, Cinética, Termodinámica

Resumen

El deterioro ambiental por la industrialización y el uso de sustancias químicas ha provocado una grave contaminación del agua, destacando metales pesados, nitratos, microplásticos, residuos industriales y colorantes como los principales contaminantes. La industria textil, por su alto consumo de colorantes, contribuye significativamente a este problema, afectando ecosistemas y salud humana. Entre las tecnologías para mitigar esta situación, la adsorción destaca por su eficiencia y bajo costo. En este contexto, la magnetita (Fe₃O₄), una ferrita con propiedades magnéticas ha mostrado gran potencial como adsorbente. Este trabajo evalúa su capacidad para remover el colorante verde malaquita. A pH neutro, se logró una remoción del 66% (53 ppm) usando 10 mg de magnetita. La cinética se ajustó al modelo de pseudo segundo orden, y las isotermas al modelo de Langmuir, con una capacidad máxima de adsorción de 2 mg/g. Los parámetros termodinámicos obtenidos fueron: ΔH = 119 kJ/mol, ΔS = 21 J/mol·K y ΔG = -16 kJ/mol.

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Ahmad, N., Arsyad, F. S., Royani, I., & Lesbani, A. (2022). Selectivity of Malachite Green on Cationic Dye Mixtures Toward Adsorption on Magnetite Humic Acid. Environment and Natural Resources Journal, 20(6), 634–643. https://doi.org/10.32526/ennrj/20/202200142

Ahmad, N., Wijaya, A., Arsyad, F. S., Royani, I., & Lesbani, A. (2024). Layered double hydroxide-functionalized humic acid and magnetite by hydrothermal synthesis for optimized adsorption of malachite green. Kuwait Journal of Science, 51(2). https://doi.org/10.1016/j.kjs.2024.100206

Ahmad, N., Zahara, Z. A., Wijaya, A., Arsyad, F. S., Royani, I., & Lesbani, A. (2023a). Fabrication and Characterization Fe3O4/Humic Acid for the Efficient Removal of Malachite Green. Science and Technology Indonesia, 8(4), 616–625. https://doi.org/10.26554/sti.2023.8.4.616-625

Ahmad, N., Zahara, Z. A., Wijaya, A., Arsyad, F. S., Royani, I., & Lesbani, A. (2023b). Fabrication and Characterization Fe3O4/Humic Acid for the Efficient Removal of Malachite Green. Science and Technology Indonesia, 8(4), 616–625. https://doi.org/10.26554/sti.2023.8.4.616-625

Ahmed, S. B., Mahmoud, N. M. R., Manda, A. A., & Refaat, H. M. (2022). Study of the optimization and mechanism for the remediation process of Malachite green dye via hybrid-based Magnetite-date’s stones. Alexandria Engineering Journal, 61(12), 9879–9889. https://doi.org/10.1016/j.aej.2022.02.065

Al-Ghouti, M. A., & Da’ana, D. A. (2020). Guidelines for the use and interpretation of adsorption isotherm models: A review. In Journal of Hazardous Materials (Vol. 393). Elsevier B.V. https://doi.org/10.1016/j.jhazmat.2020.122383

Ali, N. S., Khader, E. H., khudhur, R. H., Abdulrahman, M. A., Salih, I. K., & Albayati, T. M. (2024). Removal of anionic azo dye from wastewater using Fe3O4 magnetic nanoparticles adsorbents in a batch system. Desalination and Water Treatment, 317. https://doi.org/10.1016/j.dwt.2024.100033

Aly, S. T., Saed, A., Mahmoud, A., Badr, M., Garas, S. S., Yahya, S., & Hamad, K. H. (2024). Preparation of magnetite nanoparticles and their application in the removal of methylene blue dye from wastewater. Scientific Reports, 14(1). https://doi.org/10.1038/s41598-024-69790-w

Andrade-Guel, M. L., Cabello-Alvarado, C. J., Cano-Salazar, L. F., Ávila-Orta, C. A., & Cruz-Delgado, V. J. (2023). Recent Developments in Wastewater Treatments. In Current Status of Fresh Water Microbiology (pp. 241–263). Springer Nature Singapore. https://doi.org/10.1007/978-981-99-5018-8_10

Attallah, O. A., Al-Ghobashy, M. A., Nebsen, M., & Salem, M. Y. (2016). Removal of cationic and anionic dyes from aqueous solution with magnetite/pectin and magnetite/silica/pectin hybrid nanocomposites: Kinetic, isotherm and mechanism analysis. RSC Advances, 6(14), 11461–11480. https://doi.org/10.1039/c5ra23452b

Bayantong, A. R. B., Shih, Y. J., Ong, D. C., Abarca, R. R. M., Dong, C. Di, & de Luna, M. D. G. (2021). Adsorptive removal of dye in wastewater by metal ferrite-enabled graphene oxide nanocomposites. Chemosphere, 274. https://doi.org/10.1016/j.chemosphere.2020.129518

Cano Salazar, L. F., Martínez Luévanos, A., Claudio-Rizo, J. A., Carrillo-Pedroza, F. R., Montemayor, S. M., & Rangel Méndez, J. R. (2020). Synthesis, structural characterization and Cu(II) adsorption behavior of manganite (MnOOH) nanorods. RSC Advances, 10(1), 179–186. https://doi.org/10.1039/c9ra09652c

Giri, S. K., Das, N. N., & Pradhan, G. C. (2011). Synthesis and characterization of magnetite nanoparticles using waste iron ore tailings for adsorptive removal of dyes from aqueous solution. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 389(1–3), 43–49. https://doi.org/10.1016/j.colsurfa.2011.08.052

He, K., Chen, G., Zeng, G., Chen, A., Huang, Z., Shi, J., Peng, M., Huang, T., & Hu, L. (2018). Enhanced removal performance for methylene blue by kaolin with graphene oxide modification. Journal of the Taiwan Institute of Chemical Engineers, 89, 77–85. https://doi.org/10.1016/j.jtice.2018.04.013

Jangra, A., Singh, J., Kumar, J., Rani, K., Kumar, P., Kumar, S., Singh, D., & Kumar, R. (2023). Dye Elimination by Surface-Functionalized Magnetite Nanoparticles: Kinetic and Isotherm Studies. Biointerface Research in Applied Chemistry, 13(4). https://doi.org/10.33263/BRIAC134.325

Lima, E. C., Hosseini-Bandegharaei, A., Moreno-Piraján, J. C., & Anastopoulos, I. (2019). A critical review of the estimation of the thermodynamic parameters on adsorption equilibria. Wrong use of equilibrium constant in the Van’t Hoof equation for calculation of thermodynamic parameters of adsorption. Journal of Molecular Liquids, 273, 425–434. https://doi.org/10.1016/j.molliq.2018.10.048

Macías Erazo Karen Elizabeth. (2022). Aplicación de nanopartículas magnéticas de hierro (magnetita) en la adsorción de arsénico en aguas contaminadas. Escuela Superior Politécnica de Chimborazo.

Macías-Martínez, B. I., Cortés-Hernández, D. A., Zugasti-Cruz, A., Cruz-Ortíz, B. R., & Múzquiz-Ramos, E. M. (2016). Heating ability and hemolysis test of magnetite nanoparticles obtained by a simple co-precipitation method. Journal of Applied Research and Technology, 14(4), 239–244. https://doi.org/10.1016/j.jart.2016.05.007

Muinde, V. M., Onyari, J. M., Wamalwa, B., Wabomba, J., & Nthumbi, R. M. (2017). Adsorption of Malachite Green from Aqueous Solutions onto Rice Husks: Kinetic and Equilibrium Studies. Journal of Environmental Protection, 08(03), 215–230. https://doi.org/10.4236/jep.2017.83017

Murphy, O. P., Vashishtha, M., Palanisamy, P., & Kumar, K. V. (2023). A Review on the Adsorption Isotherms and Design Calculations for the Optimization of Adsorbent Mass and Contact Time. In ACS Omega (Vol. 8, Issue 20, pp. 17407–17430). American Chemical Society. https://doi.org/10.1021/acsomega.2c08155

Musah, M., Azeh, Y., Mathew, J., Umar, M., Abdulhamid, Z., & Muhammad, A. (2022). Adsorption Kinetics and Isotherm Models: A Review. Caliphate Journal of Science and Technology, 4(1), 20–26. https://doi.org/10.4314/cajost.v4i1.3

Qu, W., Yuan, T., Yin, G., Xu, S., Zhang, Q., & Su, H. (2019). Effect of properties of activated carbon on malachite green adsorption. Fuel, 249, 45–53. https://doi.org/10.1016/j.fuel.2019.03.058

Rajput, S., Pittman, C. U., & Mohan, D. (2016). Magnetic magnetite (Fe3O4) nanoparticle synthesis and applications for lead (Pb2+) and chromium (Cr6+) removal from water. Journal of Colloid and Interface Science, 468, 334–346. https://doi.org/10.1016/j.jcis.2015.12.008

Salem, M. A., Salem, I. A., Zaki, H. M., & El-Sawy, A. M. (2022). Elimination of Safranin-O and a binary mixture of Safranin-O and methylene blue from water by adsorption on magnetite/Ag nanocomposite. Egyptian Journal of Petroleum, 31(2), 39–49. https://doi.org/10.1016/j.ejpe.2022.05.002

Sevim, F., Lacin, O., Ediz, E. F., & Demir, F. (2021). Adsorption capacity, isotherm, kinetic, and thermodynamic studies on adsorption behavior of malachite green onto natural red clay. Environmental Progress and Sustainable Energy, 40(1). https://doi.org/10.1002/ep.13471

Tank, S. K., & Sharma, N. (2023). Adsorptive removal of malachite green using ferromagnetic sterculia gum – graftpoly(n-isopropylacrylamide-co-acrylamide)/magnetite nanocomposite. Indian Journal of Chemical Technology, 30(5), 643–655. https://doi.org/10.56042/ijct.v30i5.5193

Teo, S. H., Ng, C. H., Islam, A., Abdulkareem-Alsultan, G., Joseph, C. G., Janaun, J., Taufiq-Yap, Y. H., Khandaker, S., Islam, G. J., Znad, H., & Awual, M. R. (2022). Sustainable toxic dyes removal with advanced materials for clean water production: A comprehensive review. Journal of Cleaner Production, 332. https://doi.org/10.1016/j.jclepro.2021.130039

Thakur, P., Chahar, D., Taneja, S., Bhalla, N., & Thakur, A. (2020). A review on MnZn ferrites: Synthesis, characterization and applications. In Ceramics International (Vol. 46, Issue 10, pp. 15740–15763). Elsevier Ltd. https://doi.org/10.1016/j.ceramint.2020.03.287

Velo Facal, C. (2016). Eliminación de colorantes mediante la utilización de nanopartículas. Departamento de Química Física e Enxeñaría Química I.

Wang, K., Kou, Y., Wang, K., Liang, S., Guo, C., Wang, W., Lu, Y., & Wang, J. (2023). Comparing the adsorption of methyl orange and malachite green on similar yet distinct polyamide microplastics: Uncovering hydrogen bond interactions. Chemosphere, 340. https://doi.org/10.1016/j.chemosphere.2023.139806

Zahara, Z. A., Royani, I., Palapa, N. R., Mohadi, R., & Lesbani, A. (2023). Treatment of Methylene Blue Using Ni-Al/Magnetite Biochar Layered Double Hydroxides Composite by Adsorption. Bulletin of Chemical Reaction Engineering and Catalysis, 18(4), 659–674. https://doi.org/10.9767/bcrec.20049

Zheng, Z., Wang, S., Yang, F., & Pan, J. (2024). Controlled surface multifunctional groups over halloysite nanotube enabling reinforced lead adsorption in vitro. Separation and Purification Technology, 339. https://doi.org/10.1016/j.seppur.2024.126632

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Publicado

2025-10-05

Cómo citar

de la Peña Aguirre, D., Múzquiz Ramos, E. M., Ríos Hurtado, J. C., Claudio Rizo, J. A., Gallardo Heredia, M., & Cano Salazar, L. F. (2025). Adsorción de Verde Malaquita Utilizando Magnetita: Estudio Cinético y Termodinámico. Tópicos De Investigación En Ciencias De La Tierra Y Materiales, 12(12), 70–77. https://doi.org/10.29057/aactm.v12i12.15261

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