Polioxometalatos de cobre basados en estructuras tipo Strandberg (P2Mo5): Síntesis y caracterización

A. López-Benítez; A. G. Mijares-Alvarado; A. R. Tapia-Benavides; A. Guevara-Lara

doi:10.29057/aactm.v13i13.18066

Autores/as

A. López-Benítez Instituto Politécnico Nacional https://orcid.org/0000-0002-1535-8115
A. G. Mijares-Alvarado Universidad Autónoma del Estado de Hidalgo https://orcid.org/0009-0003-7973-8103
A. R. Tapia-Benavides Universidad Autónoma del Estado de Hidalgo https://orcid.org/0000-0002-9848-3789
A. Guevara-Lara Universidad Autónoma del Estado de Hidalgo https://orcid.org/0000-0002-5658-9884

DOI:

https://doi.org/10.29057/aactm.v13i13.18066

Palabras clave:

Polioxometalatos, estructura de Strandberg, catalizadores, nanocúmulos, compuestos de molibdeno

Resumen

Dentro de la gran familia de polioxometalatos, los polioxometalatos basados en estructuras tipo Strandberg no han sido suficientemente estudiados y reportados. En este trabajo, un polioxometalato de cobre basado en una estructura tipo Strandberg ANIH₂[{Cu(ANI)₂(H₂O)}₂ (PO₄)₂Mo₅O₁₅](ANI) 2H₂O fue sintetizado y caracterizado. Con el propósito de entender las interacciones entre el cobre y el fragmento de Strandberg [P₂Mo₅], el compuesto fue caracterizado durante todo el proceso de síntesis usando espectroscopía Infrarroja por transformada de Fourier (FT-IR) y espectroscopía de reflectancia difusa (UV-vis). Los resultados de UV-vis sugieren que el Cu²⁺exhibe ambas simetrías, octaédrica (Oh) y octaédrica distorsionada (Oh-dis), mientras que los de FT-IR muestran las bandas características de la estructura de Strandberg. Este estudio muestra que ambos análisis espectroscópicos pueden ser usados para confirmar la formación de un polioxometalato.

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Citas

Ammam, M. (2016). Polyoxometalates: formation, structures, principal properties, main deposition methods and application in sensing. Journal of Materials Chemistry A, 1, 6291–6312. DOI: 10.1039/C3TA01663C

Annamma, J., Daizy, P., Cabeza, A., & Devanarayanan, S. (2002). Vibrational analysis of lead (II) phenylphosphonate Pb(O3PC6H5). Indian Journal of Physics,76B, 213–215

Baaalla, N., Ammari, Y., Hlil, E. K., Abid, S., Masrour R., Benyoussef, A., & Kenz, A. (2021). The novel material based on Strandberg type hybrid complex (C6H10N2)2[Co(H2O)4P2Mo5O23] 6H2O experimental and simulations investigation on electronic, optical, and magnetocaloric properties. Ceramics International, 47, 2338–2346. DOI: 10.1016/J.CERAMINT.2020.09.076

Borrás-Almenar, J., Coronado, E., Müller, A., & Pope, M. (2003). Polyoxometalate Molecular Science. Springer, Dordrecht. DOI: 10.1007/978-94-010-0091-8

Bravo-Suárez, J. J., Subramaniam, B., & Chaudhari, R. V. (2012). Ultraviolet-visible spectroscopy and temperature programmed techniques as tools for structural characterization of Cu in CuMgAlOx mixed metal oxides. The Journal of Physical Chemistry, 116, 18207–18221. DOI: 10.1021/jp303631v

Bugay, D. E. (2001). Characterization of the solid-state: spectroscopic techniques. Advanced Drug Delivery Reviews, 48, 43-65. DOI: 10.1016/S0169-409X(01)00101-6

Cao, R., Liu, S., Cao, J., Wang, L., Tang, Q., Liu, Y., & Ren, Y. (2008). An organic-inorganic hybrid compound constructed by Strandberg-type polyoxoanions and transition metal coordination complexes. Journal of Molecular Structure, 888, 307–312. DOI: 10.1016/J.MOLSTRUC.2007.12.043

Crivello, M., Pérez, C., Herrero, E., Ghione, G., Casuscelli, S., & Rodríguez-Castellón, E. (2005). Characterization of Al-Cu and Al-Cu-Mg mixed oxides and their catalytic activity in dehydrogenation of 2-octanol. Catalysis Today, 107–108, 215–222. DOI: 10.1016/J.CATTOD.2005.07.168

Fournier, M., Louis, C., Che, M., Chaquin, P., & Masure, D. (1989). Polyoxometallates as models for oxide catalysts: Part I. An UV-visible reflectance study of polyoxomolybdates: Influence of polyhedral arrangement on the electronic transitions and comparison with supported molybdenum catalysts. Journal of Catalysis, 119, 400–414. DOI: 10.1016/0021-9517(89)90170-X

Ftini, M. M. (2017). Hydrothermal synthesis and characterization of a new Strandberg-type diphosphopentamolybdate (C6N3H18)2[P2Mo5O23] 6H2O. Crystallography Reports, 62, 1138–1143. DOI: 10.1134/S1063774517070094

Fukaya, K., Srifa, A., Isikawa, E., & Naruke, H. (2010). Synthesis and structural characterization of polyoxometalates incorporating with anilinium cations and facile preparation of hybrid film. Journal of Molecular Structure, 979, 221–226. DOI: 10.1016/J.MOLSTRUC.2010.06.030

Goebbert, D., Garand, E., Wende, T., Bergmann, R., Meijer, G., Asmis, K. R., & Neumark, D. M. (2009). Infrared spectroscopy of the microhydrated nitrate ions NO3-(H2O)1-6. The Journal of Physical Chemistry A, 113, 7584–7592. DOI: 10.1021/jp9017103

Guevara-Lara, A., Bacaud, R., & Vrinat, M. (2007). Highly active NiMo/TiO2-Al2O3 catalysts: Influence of the preparation and the activation conditions on the catalytic activity. Applied Catalysis A: General, 328, 99–108. DOI: 10.1016/J.APCATA.2007.05.028

Jangir, R., Ansari, M., Kaleeswaran, D., Rajaraman, G., Palaniandavar, M., & Murugavel, R. (2019). Unprecedented Copper (II) complex with a topoquinone-like moiety as a structural and functional mimic for copper amine oxidase: Role of Copper (II) in the genesis and amine oxidase activity. ACS Catalysis, 9, 10940–10950. DOI: 10.1021/acscatal.9b02326

Ji, Y., Huang, L., Hu, J., Streb, C., & Song, Y. F. (2015). Polyoxometalate-functionalized nanocarbon materials for energy conversion, energy storage and sensor systems. Energy & Environmental Science, 8, 776–789. DOI: 10.1039/C4EE03749A

Katsoulis, D. E. (1998). A survey of applications of polyoxometalates. Chemical Reviews, 98, 359–388. DOI: 10.1021/cr960398a

Kwak, W., Pope, M. T., & Scully, T. F. (1975). Stable organic derivatives of heteropoly anions, pentamolybdobisphosphonates. Journal of the American Chemical Society, 97, 5735–5738. DOI: 10.1021/ja00853a017

Li, X. M., Chen, Y. G., Shi, T., Zhou, S., & Tang, Q. (2014). Coordination of the carboxylate of the functionalized Strandberg anion in a three-dimensional covalence framework. Inorganic Chemistry Communications, 50, 70–74. DOI: 10.1016/J.INOCHE.2014.10.022

Long, D. L., Tsunashima, R., & Cronin, L. (2010). Polyoxometalates: Building blocks for functional nanoscale systems. Angewandte Chemie International Edition, 49, 1736–1758. DOI: 10.1002/anie.200902483

López-Benítez, A., Guevara-Lara, A., & Berhault, G. (2019). Nickel-containing polyoxotungstates based on [PW9O34]9- and [PW10O39]13- Keggin lacunary anions supported on Al2O3 for dibenzothiophene hydrodesulfurization application. ACS Catalysis, 9, 6711–6727. DOI: 10.1021/acscatal.9b01460

Lu, X., Wang, X., Li, P., Pei, X., & Ye, C. (2008). Self-assembly of two novel 1D chains constructed from {P2Mo5} phosphomolybdate clusters linked through copper (II) complexes. Journal of Molecular Structure, 872, 129–134. DOI: 10.1016/J.MOLSTRUC.2007.02.027

Qu, X., Feng, H., Ma, C., Yang, Y., & Yu, X. (2017). Synthesis, crystal structure and antitumor activity of a novel 3D supramolecular compound constructed from Strandberg-type polyoxometalate and benzimidazole. Inorganic Chemistry Communications, 81, 22–26. DOI: 10.1016/J.INOCHE.2017.04.023

Shi, C., Gao, X. L., Zhou, K., Cui, D., Qu, H. P., Ji, J. Y., & Bi, Y. (2017). An inorganic-organic hybrid constructed from Keggin polyoxoanions and benzotriazole ligands modulated by two dinuclear silver (I) clusters. Polyhedron, 138, 232–238. DOI: 10.1016/J.POLY.2017.09.031

Shukla, U. (2025). Fourier transform infrared spectroscopy: A power full method for creating fingerprint of molecules of nanomaterials. Journal of Molecular Structure, 1322, 140454. DOI: 10.1016/j.molstruc.2024.140454

Strandberg, R. (1973). Multicomponent Polyanions. The molecular and crystal structure of Na6Mo5P2O23(H2O)13, a compound containing sodium-coordinated pentamolybdodiphosphate anions. Acta Chemica Scandinavica, 27, 1004-1018. DOI: 10.3891/acta.chem.scand.27-1004

Tabbì, G., Giuffrida, A., & Bonomo, R. P. (2013). Determination of formal redox potentials in aqueous solution of copper (II) complexes with ligands having nitrogen and oxygen donor atoms and comparison with their EPR and UV-Vis spectral features. Journal of Inorganic Biochemistry, 128, 137–145. DOI: 10.1016/J.JINORGBIO.2013.07.035

Thomas, J., Kumar, D., & Ramanan, A. (2013). Crystallization of phosphomolybdate clusters mediated by copper azole complexes: Influence of pH and temperature. Inorganica Chimica Acta, 126–135. DOI: 10.1016/J.ICA.2012.10.034

Wang., C, Shi, J., & Zhou, B.B.B. (2018). Three pure inorganic materials based on Strandberg-type phosphomolybdate and different transition metal linkers. Journal of Coordination Chemistry, 71, 3970-3979. DOI: 10.1080/00958972.2018.1542137

Wang, S. M., & Yang, G. Y. (2015). Recent advances in polyoxometalate-catalyzed reactions. Chemical Reviews, 115, 4893–4962. DOI: 10.1021/cr500390v

Wienold, J., Jentoft, R. E., & Ressler, T. (2003). Structural investigation of the thermal decomposition of ammonium heptamolybdate by in situ XAFS and XRD. European Journal of Inorganic Chemistry, 1058–1071. DOI: 10.1002/ejic.200390138

Yaffa, L., Kama, A.B., Sall, M.L., Diop, C.A., Sidibé, M., Giorgi, M., Diop, M., & Gautier, R. (2020). Role of the organic counterions on the protonation of Strandberg-type phosphomolybdates. Polyhedron, 191, 114795. DOI: 10.1016/j.poly.2020.114795

Zhang, J., Huang, Y., Li, G., & Wei, Y. (2019). Recent advances in alkoxylation chemistry of polyoxometalates: From synthetic strategies, structural overviews to functional applications. Coordination Chemistry Reviews, 378, 395–414. DOI: 10.1016/J.CCR.2017.10.025

Zhao, H., Li, J., Fang, Y., Chang, B., Meng, Q., Li, M., Wang, C., & Zhu, X. (2020). Synthesis, characterization and bioactivities of a new covalent copper (II) compound derived from {P2MO5O23}6- and thiosemicarbazones. Bioorganic & Medicinal Chemistry Letters, 30, 126781. DOI: 10.1016/J.BMCL.2019.126781