Synthesis and photocatalytic evaluation of Bi25FeO40 under visible light irradiation

Keywords: Photocatalysis, Bi25FeO40, Photocatalytic activity, Visible light, Degradation efficiency, recoverable

Abstract

In this study, the crystalline structure, photocatalytic activity and magnetic properties of Bi25FeO40 were discussed. The Bi25FeO40 powder was produced by high-energy ball milling and annealing at 700°C. The crystal structure was analyzed by X ray diffraction, showing a Bi25FeO40 phase with high purity (100 %) and cubic crystalline structure that belongs to I23 space group. The photocatalytic activity was evaluated measuring the degradation efficiency of crystal violet (CV) dye under visible light irradiation (420-780 nm), showing a degradation efficiency of 34% after 210 minutes of light irradiation, which suggest that Bi25FeO40 could operate under solar light. According to magnetic characterization, it reveals a ferrimagnetic behavior with a magnetization of 0.054 emu/g. It confirms the synthesis of a magnetically recoverable photocatalyst.

Downloads

Download data is not yet available.

References

Michelle AN, Elsayed MZ, Azaan SW, Alexander VB, Vincent JC, William AR, Randy LL, Joshua LC, Leonidas GB, Marc RK. Converting Light Energy to Chemical Energy: A New Catalytic Approach for Sustainable Environmental Remediation. ACS Omega 2016; 1(1): 41–51.

Rajasulochana P, Preethy V, Comparison on efficiency of various techniques in treatment of waste and sewage water – A comprehensive review, Resources-Efficient Technology 2016; 2: 1-10.

Kalikeri S, Kodialbail VS, Solar light-driven photocatalysis using mixed-phase bismuth ferrite (BiFeO3/Bi25FeO40) nanoparticles for remediation of dye-contaminated water: kinetics and comparison with artificial UV and visible light-mediated photocatalysis. Envir. Sci. and Pollut. Res. 2018; 14: 13881-13893.

Shasha Z, Dunwei W. Photocatalysis: Basic Principles, Diverse Forms of Implementations and Emerging Scientific Opportunities. Advanced Energy Materials 2017; 7(23): 1-24.

Kumari P, Khare N, Structural, Optical and Magnetic Properties of Bi25FeO40 Nanoparticles Synthesized by Hydrothermal Method. Recent Trends in Materials and Devices 2016, 178: 139–143.

Radaev SF, Muradian LA, Simonov VI, Atomic structure and crystal chemistry of sillenites: Bi12(Bi3+0.50Fe3+0.50)O19.50 and Bi12(Bi3+0.67Zn2+0.33)O19.33. Acta Cryst.1991; 47: 1-6.

Koferstein R, Buttlar T, Ebbinghaus SG, Investigations on Bi25FeO40 powders synthesized by Hydrothermal and combustion-like processes. Journal of Solid State Chemistry 2014; 217: 50-56.

Chmyrev VI, Skorikov VM, Larina EV, Doping effect on the optical, electro-optic, and photoconductive properties of Bi12Mo20 (M= Ge,Si,Ti). Inorganic Materials 2006; 42; 381-392.

Ji W, Li M, Zhang G, Wang P, Controlled synthesis Bi25FeO40 with different morphologies: growth mechanism and enhanced photo-Fenton catalytic property. Dalton Transactions 2017; 46(32): 10586-10593.

Basith MA, Ahsan R, Zarin I, Jalil MA, Enhanced photocatalytic dye degradation and hydrogen production ability of Bi25FeO40-rGO nanocomposite and mechanism insight. Scientific Reports 2018; 8: 1-11.

Zatsiupa AA, Bashkiro LA, Troyanchuk IO, Petrov GS, Galya A.I, Lobanovsky LS, Truhanov SV, Magnetization, magnetic susceptibility, effective magnetic moment of Fe3+ ions in Bi25FeO39 ferrite. Journal of Solid State Chemistry 2014; 212: 147-150.

Aiwu S, Huan C, Chunyan S, Fang J, Xin W, Yongsheng F, Magnetic Bi25FeO40-graphene catalyst and its high visible-light photocatalytic performance. RSC Advances 2013; 3(13): 1-9.

Shundong B, Dengrong C, Jianmin L, Shengwen Y, Dengren J, Jinrong C, Structure and photocatalytic properties of Bi25FeO40 crystallites derived from the PEG assisted sol-gel methods. MRS Proceedings 2011; 1324: 1-17.

Zhang CY, Sun HJ, Chen W, Zhou J, Li B, Wang YB, Hydrothermal Synthesis and Photo-catalytic Property of Bi25FeO40 Powders. 2009 18th IEEE International Symposium on the Applications of Ferroelectrics 2009; 1-3.

Published
2020-10-05
How to Cite
Betancourt Cantera, L. G., Bolarín Miró, A. M., Ramírez Cardona, M., Sánchez de Jésus, F., & Betancourt Cantera, J. A. (2020). Synthesis and photocatalytic evaluation of Bi25FeO40 under visible light irradiation. Tópicos De Investigación En Ciencias De La Tierra Y Materiales, 7(7), 28-32. https://doi.org/10.29057/aactm.v7i7.6179