Exhaustive characterization of a natural zeolite Clinoptilolite-type 3 from the state Hidalgo
Abstract
Two samples of zeolite from the company Moliendas y Molinos de Pachuca S.A. de C.V., were characterized by the techniques of X-ray diffraction (XRD), scanning electron microscopy (SEM - EDS), X-ray fluorescence, adsorption, thermogravimetry (TGA) and Differential Scanning Calorimetry (DSC). The type of zeolite was determined according to Alietti's classification based on the analysis obtained by the Mumpton method on thermal stability. The chemical equation per unit cell and the Si/Al ratio were corroborated with the results obtained by applying the empirical parameter Γ. The morphology and particle size are described, as well as the size and shape of the pores.
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D. M. Flanagan, «Zeolites (Natural),» U.S. Geological Survey, Mineral Commodity Summaries, February 2019. [En línea]. Available: https://prd-wret.s3-us-west-2.amazonaws.com/assets/palladium/production/atoms/files/ mcs-2019-zeoli.pdf.
Silva G, Galeano E, Correa J. Compliance with the treatment. Acta Médica Colombiana 2005; 30(4): 268–73.
L. Bacakova, . M. Vandrovcova, . I. Kopova y I. Jirka, «Applications of zeolites in biotechnology and medicine – a review,» Biomaterials Science, vol. 6, pp. 974-989, 2018.
«Rota Mining Corporation,» 2020. [En línea]. Available: https://www.rotamining.com/?lang=fr.
J. L. Costafreda Mustelier, D. A. Martín Sánchez y J. L. Costafreda Velázquez, Las zeoLitas naturales de Iberoamérica, Fundación Gómez Pardo, 2018.
D. M. Flanagan, «USGS Mineral Commodity Specialist, National Minerals Information Center,» [En línea]. Available: https://www.usgs.gov/centers/nmic/zeolites-statistics-and-information.
F. A. Mumpton, «First reported ocurrence of zeolites in sedimentary rocks of Mexico,» American MIneralogist, pp. 287-290, 1973.
A. Aquino, Estudio de caracterización mineralógica de la cantera oaxaqueña, Fomento minero, 1991.
L. F. Resendiz, «Canteras oaxaqueñas, ¿Algo más que un material de construcción?.,» Revista CONACYT, pp. 5-10, 1992.
T. M. Candelaria , Informe final de la exploración realizada en el proyecto: Zeolitas Laollaga, municipio de Santiago Laollaga, Consejo de recursos minerales, 1994.
M. d. C. Calderón Velázquez, Mineralogía, petrografía y química de las rocas volcánicas zeolitizadas del estado de Oaxaca: implicación económica., México, D.F., 2004.
M. Ostrooumov, Zeolitas de México: diversidad mineralógica y aplicaciones., 2006.
D. L. Bish y J. M. Boak, «Clinoptilolite-Heulandite Nomenclature,» Reviews in Mineralogy and Geochemistry, pp. 207 - 216, 2001.
F. A. Mumpton , «Clinoptilolite redefined,» The American mineralogist, vol. 45, pp. 351 - 369, Marzo - Abril 1960.
A. Alietti, «Polymorphism and crystal-chemistry of Heulandites and Clinoptilolites,» The American Mineralogist, vol. 57, pp. 1448 - 1462, 1972.
G. P. Valueva , «Chemical parameters for classification of heulandites,» Russian Geol. Geophys, pp. 1-4, 1994.
M. Ostrooumov, P. Cappelletti y R. de’Gennaro, «Mineralogical study of zeolite from New Mexican deposits, (Cuitzeo area, Michoacan, Mexico),» Applied Clay Science, vol. 55, pp. 27-35, 2012.
D. S. Coombs, A. Alberti, T. Armbruster, G. Artioli, C. Colella, E. Galli, J. D. Gice, F. Liebau, J. A. Mandarino, H. Minato, E. H. Nickel, E. Passaglia, D. R. Peacor, S. Quartieri, R. Rinaldi, M. Ross, R. A. Sheppard, E. Tillmanns y G. Vezzalini, « Recommended nomenclature for zeolite minerals: report of the subcommittee on zeolites of the International Mineralogical Association, commission on new Minerals and Mineral names,» The Canadian Mineralogist, vol. 35, pp. 1571-1606, 1997.
S. J. Chipera y J. A. Apps, «Geochemical Stability of Natural Zeolites,» de Natural zeolites: Ocurrence, properties, applications, vol. 45, 2001, pp. 117 - 161.
K. Sing, D. H. Everett, R. A. W. Haul , L. Moscou , R. A. Pierotti, J. Rouquerol y T. Siemieniewska, «Reporting physisoption data for gas/solid systems with special reference to the determination of surface area and porosity,» Pure & Appl. Chem., pp. 603-619, 1985.
F. Rouquerol , J. Rouquerol y K. W. Sing, Adsoprtion by powders and porous solids: principles, methodology and applications, Francia: Academic Press, 1999.
M. Thommes, K. Kaneko, A. Neimark, J. Olivier, F. Rodriguez-Reinoso, J. Rouquerol y K. S. W. Sing, «Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report),» Pure Appl. Chem, pp. 1051 - 1.69, 2015.
M. Mahdi LabanI, R. Rezaee, A. Saeedi y A. Al Hinai, «Evaluation of pore size spectrum of gas shale reservoirs using low pressure nitrogen adsorption, gas expansion and mercury porosimetry: A case study from the Perth and Canning Basins, Western Australia,» Journal of Petroleum Science and Engineering, pp. 7 - 16, 2013.
R. Bardestan, G. S. Patience y . S. Kaliaguine, «Experimental methods in chemical engineering: specific surface area and pore size distribution measurements—BET, BJH and DFT,» The Canaidan Journal of Chemical Engineering, pp. 2781 - 2791, 2019.
N. Saeid y M. Parvini, «Accuracy of Dubinin-Astakhov and Dubinin-Radushkevich Adsorption Isotherm Models in Evaluating Micropore Volume of Bentonite,» Periodica Polytechnica Chemical Engineering, pp. 123 - 129, 2016.
J. Kenvin , Characterization of Powders and Porous Materials with Pharmaceutical Excipinent Case Studies, 2008.
F. J. Sotomayor, . K. A. Cychosz y M. Thommes, «Characterization of Micro/Mesoporous Materials by Physisorption: Concepts and Case Studies,» Accounts of Materials & Surface Research, vol. 3, nº 2, pp. 34 - 35, 2018.
E. Galli, G. Gottardi, H. Mayer, A. Preisinger y A. Passaglia, «Acta Cristalogr. Sect. B 39,» 1983, pp. 189-197.
V. K. Pecharsky y P. Y. Zavalij, «Fundamentals of Powder Diffraction and Structural,» de Characterization of Materials, Binghamton, New York, Springer, 2005, pp. 171-182.
D. Rosentha, Surface area determination - physisorption and chemisorption, Germany.
