Efecto de la temperatura de tratamiento térmico en las propiedades magnéticas, ópticas y fotocatalíticas de NiFe2O4 sintetizada por molienda de alta energía

Marcos Ulises Monrroy-López; Félix Sánchez De Jesús; Ana María Bolarín Miró; Antonia Martínez Luévanos; Márius Ramírez Cardona; Omar Rosales González

doi:10.29057/aactm.v9i9.9307

Marcos Ulises Monrroy-López Universidad Autónoma del Estado de Hidalgo https://orcid.org/0000-0002-0354-2804
Félix Sánchez De Jesús Universidad Autónoma del Estado de Hidalgo https://orcid.org/0000-0002-9453-1755
Ana María Bolarín Miró Universidad Autónoma del Estado de Hidalgo https://orcid.org/0000-0002-2199-1208
Antonia Martínez Luévanos Universidad Autónoma de Coahuila https://orcid.org/0000-0003-3499-1693
Márius Ramírez Cardona Universidad Autónoma del Estado de Hidalgo https://orcid.org/0000-0003-4376-3377
Omar Rosales González Universidad Autónoma del Estado de Hidalgo https://orcid.org/0000-0003-2948-438X

DOI: https://doi.org/10.29057/aactm.v9i9.9307

Keywords: Ferrites, NiFe2O4, Photocatalyst, Heat treatment, Hig-energy ball milling

Abstract

This work reports the study of the effect of annealing temperature over structure and magnetic, optic and photocatalytic properties of nickel ferrite (NiFe₂O₄) synthetized by high-energy ball milling. X ray diffraction technique (XRD) and Rietveld refinement confirm the formation of NiFe₂O₄ finding Fe₂O₃ as secondary phase at annealing temperature below 1273 K. Vibrating sample magnetometry (VSM) reveal an increase in magnetization values as annealing temperature increase, attributed to changes in cation distribution of Fe³⁺and Ni²⁺magnetic ions into crystal structure. Bandgap values calculated form diffuse reflectance spectroscopy (DRS) show that all samples absorb light in visible range. Photocatalytic tests show degradation efficiencies around 60 % for all samples being NiFe2O4 a good alternative for its use as photocatalysts under visible light and its magnetic recovery.

Downloads

Download data is not yet available.

References

Betancourt-Cantera, L. G., Fuentes, K. M., Bolarín-Miró A. M., Aldabe-Bilmes S., Cortés-Escobedo C. A., and Sánchez-De Jesús F., (2020). Enhanced Photocatalytic Activity of BiFeO3 for Water Remediation via the Addition of Ni2+. Materials Research Bulletin 132, 111012. DOI: 10.1016/j.materresbull.2020.111012.

Chandrika, M., Ravindra A. V., (2019). Studies on Structural and Optical Properties of Nano ZnFe2O4 and ZnFe2O4-TiO2 Composite Synthesized by Co-Precipitation Route. Materials Chemistry and Physics 230, 107–13. DOI: 10.1016/j.matchemphys.2019.03.059.

Dhiman, P., Rana G., Kumar A., Sharma G., (2021). Nanostructured Magnetic Inverse Spinel Ni–Zn Ferrite as Environmental Friendly Visible Light Driven Photo-Degradation of Levofloxacin. Chemical Engineering Research and Design 175, 85–101. DOI: 10.1016/j.cherd.2021.08.028.

Garcés, L. F., Mejía E. A., Santamaría J. J.. (2004). La fotocatálisis como alternativa para el tratamiento de aguas residuales. Revista Lasallista 1, 83–92.

Garcia-Muñoz, P., Fresno F., De la Peña O’Shea V. A., Keller N.. (2020). Ferrite Materials for Photoassisted Environmental and Solar Fuels Applications. Topics in Current Chemistry 378, 378:6. DOI: 10.1007/s41061-019-0270-3.

Granone, L. I., Dillert R., Heitjans P., Bahnemann D. W., (2019). Effect of the Degree of Inversion on the Electrical Conductivity of Spinel ZnFe2O4. ChemistrySelect 4, 1232–39. DOI:10.1002/slct.201804062.

Hirthna, S. S., Rajan P. I., Adinaveen T., (2018). Synthesis and Characterization of NiFe2O4 Nanoparticles for the Enhancement of Direct Sunlight Photocatalytic Degradation of Methyl Orange. Journal of Superconductivity and Novel Magnetism 31, 3315–22. DOI:10.1007/s10948-018-4601-3.

Ismael, M., (2021). Ferrites as Solar Photocatalytic Materials and Their Activities in Solar Energy Conversion and Environmental Protection: A Review. Solar Energy Materials and Solar Cells 219, 110786. DOI:10.1016/j.solmat.2020.110786.

Kisch, H., (2013). Semiconductor Photocatalysis - Mechanistic and Synthetic Aspects. Angewandte Chemie-International Edition 52, 812–47. DOI:10.1002/anie.201201200.

Majid, F., Rauf J., Ata S., Bibi I., Malik A., Ibrahim S. M., Ali A., (2021). Synthesis and Characterization of NiFe2O4 Ferrite: Sol–Gel and Hydrothermal Synthesis Routes Effect on Magnetic, Structural and Dielectric Characteristics. Materials Chemistry and Physics 258, 123888. DOI:10.1016/j.matchemphys.2020.123888.

Mera Benavides, D. A., Mera Benavides A.C., (2011). Tratamiento Fotocatalítico de Aguas Residuales Generadas En Laboratorios Con Presencia Del Indicador Verde de Bromocresol. Revista Lasallista de Investigacion 8, 28–41.

Nevárez-Martínez, M. C., Espinoza-Montero P. J., Quiroz-Chávez F. J., Ohtani B., (2017). Fotocatálisis: Inicio, Actualidad y Perspectivas a Través Del TiO2. Avances En Química. Avances En Química 12, 45–59.

Pottker, W. E., Ono R., Cobos M.A., Hernando A., (2018). Influence of Order-Disorder Effects on the Magnetic and Optical Properties of NiFe2O4 Nanoparticles. Ceramics International 44, 17290–97. DOI: 10.1016/j.ceramint.2018.06.190.

Rodriguez, J., Candal R. J., Estrada W., Blesa M. A., (2005). El Fotocatalizador : Síntesis, Propiedades y Limitaciones. Tecnologías Solares Para La Desinfección y Descontaminación Del Agua, 139–145. https://www.psa.es/webesp/projects/solarsafewater/curso.php.

Rosales-González, O., Sánchez-De Jesús F., Camacho-González M.A., Cortés-Escobedo C.A., Bolarín-Miró A.M., (2020). Synthesis of Magnetically Removable Photocatalyst Based on Bismuth Doped YFeO3. Materials Science and Engineering: B 261, 114773. DOI:10.1016/j.mseb.2020.114773.

Shannon, R. D., (1976). Revised Effective Ionic Radii and Systematic Studies of Interatomie Distances in Halides and Chaleogenides. Acta Crystallographica A 32, 751–67. DOI: 10.1023/A:1018927109487

Silva, E., Ouriques-Brasileiro I. L., Stumpf-Madeira V., (2020). Reusable CuFe2O4-Fe2O3 catalyst Synthesis and Application for the Heterogeneous Photo-Fenton Degradation of Methylene Blue in Visible Light. Journal of Environmental Chemical Engineering 8, 104132 DOI:10.1016/j.jece.2020.104132.

Slimani, Y., Almessiere M. A., Güner S., Tashkandi N. A., Baykal A., Sarac M. F., Nawaz M., Ercan I., (2019). Calcination Effect on the Magneto-Optical Properties of Vanadium Substituted NiFe2O4 Nanoferrites. Journal of Materials Science: Materials in Electronics, 30. 0123456789.DOI: 10.1007/s10854-019-01243-x.

Soon, Ai Ni, Hameed B. H., (2011). Heterogeneous Catalytic Treatment of Synthetic Dyes in Aqueous Media Using Fenton and Photo-Assisted Fenton Process. Desalination 269, 1–16.DOI:10.1016/j.desal.2010.11.002.

Vara Prasad, B. B., Ramesh K. V., Srinivas A., (2018). Structural and Magnetic Properties of Nanocrystalline Nickel Ferrite (NiFe2O4) Synthesized in Sol-Gel and Combustion Routes. Solid State Sciences 86, 86–97. DOI:10.1016/j.solidstatesciences.2018.10.008.