Biotechnological system for the reduction of chromium (VI) in wastewater
Keywords:
Chromium (VI), Bio filter, Chelation, antioxidants, Biotechnology
Abstract
Due to its toxicity, the Cr (VI) in water and sediment of rivers represents a serious health problem for people who use these flowing, whose exposure is related to diseases such as delays in development, cases of different types of cancer, damage to kidneys, and even with cases of death [1, 2]. This paper describes the application of a system bioreductor for the decrease of hexavalent chromium in wastewater, through a bio filter composed of Agave potatorum fiber, polar organic extracts rich in ascorbic acid, citric acid and flavonoids, metabolites with a high antioxidant capacity and ligand N- donator Tris-(2-(((1E, 2E)-3-fenilaliliden) amino)ethyl)imine obtained by green chemistry [3-5] and characterized by spectroscopic techniques of routine: mass spectroscopy by electron impact, FT-IR and UV-Vis. The latter compound presents an important activity chelating over ion Cr (VI) that is reduced and absorbed by the biotechnology system on deleting it from the water with an efficiency of
95%, evaluating the results by UV-Vis spectrophotometry.
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References
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Bustillos en Chihuahua, México. Investigación no publicada, 2011.
[3] Anastas, P. a. (2000). Green Chemestry: Theory and Practice. J. C. Green Chemistry: Theory and Practice, New York, Oxford University, pp. 30-36.
[4] Newman Stephen G., Jensen Klays F. Green Chem., 2013, 15, 1456-1472
[5] Clark James, Sheldon Roger, Raston Colin, Poliakoff Martyn, Leitner Walter, Green Chem., 2014,16, 18-23
[6] Gutiérrez, R. L., Rubio-Arias, H., Quintana, R., Ortega, J. A., & Gutierrez, M. International journal of environmental research and public health, 2008, 5(2), 91-98.
[7] Reyes-Gutiérrez, L. R., Romero-Guzmán, E. T., Olmos-Salinas, M. G., & Rodríguez-Castillo, R. Revista Mexicana de Ciencias Geológicas, 2009, 26(1), 104-116.
[8] Fiedler, S., Siebe, C., Herre, A., Roth, B., Cram, S., & Stahr, K., Water, air, and soil pollution, 2009, 197(1-4), 35-47.
[9] Rubio-Arias, H., Quintana, C., Jimenez-Castro, J., Quintana, R., & Gutierrez, M. International journal of environmental research and public health, 2010, 7(5), 2071-2084.
[10] Rubio-Arias, H., Rey, N. I., Quintana, R. M., Nevarez, G., & Palacios, O. International journal of environmental research and public health, 2011, 8(6), 2386-2400. 6
[11] Villalobos-Aragón, A., Ellis, A. S., Armienta, M. A., Morton-Bermea, O., & Johnson, T. M. Applied Geochemistry, 2012, 27(9), 1783-1794.
[12] Steffy, D. A., Nichols, A. C., Morgan, L. J., & Gibbs, R. Water, Air, & Soil Pollution, 2013, 224(11), 1-11.
[13] Wise Jr, J. P., Wise, J. T., Wise, C. F., Wise, S. S., Gianios Jr, C., Xie, H., & Wise Sr, J. P. Environmental science & technology, 2015, 48(5), 2997-3006.
[14] Cai, Y., Rooker, J. R., Gill, G. A., & Turner, J. P. Journal of Fisheries and Aquatic Sciences, 2007, 64(3), 458-469.
[15] Guentzel, J. L., Portilla, E., Keith, K. M., & Keith, E. O. Science of the Total Environment, 2007, 388(1), 316-324.
[16] Trefry, J. H., Trocine, R. P., McElvaine, M. L., Rember, R. D., & Hawkins, L. T. Environmental geology,2007, 53(2), 375-385.
[17] García-Hernández, J., Cadena-Cárdenas, L., Betancourt-Lozano, M., García-De-La-Parra, L. M., García-Rico, L., & Márquez-Farías, F. Toxicological & Environmental Chemistry, 2007, 89(3), 507- 522. 7
[18] Lewis, M., & Chancy, C. Chemosphere, 2008, 70(11), 2016-2024.
[19] Gutiérrez-Galindo, E. A., Casas-Beltrán, D. A., Munoz-Barbosa, A., Daesslé, L. W., Segovia-Zavala, J. A., Macías-Zamora, J. V., & Orozco-Borbón, M. V. Bulletin of environmental contamination and toxicology, 2008, 80(2), 123-127.
[20] DeLaune, R. D., Devai, I., Hou, A., & Jugsujinda, A. Soil & Sediment Contamination, 2008, 17(2), 98-106.
[21] Osuna-Martínez, C. C., Páez-Osuna, F., & Alonso-Rodríguez, R. Bulletin of environmental contamination and toxicology, 2012, 85(3), 339-343.
[22] Shah, A. Q., Kazi, T. G., Baig, J. A., Afridi, H. I., Kandhro, G. A., Khan, S., & Wadhwa, S. K. Food and Chemical Toxicology, 2010, 48(6), 1550-1554.
[23] Leal-Acosta, M. L., Shumilin, E., Mirlean, N., Sapozhnikov, D., & Gordeev, V. Bulletin of environmental contamination and toxicology, 2010, 85(6), 609-613.
[24] Macias Medrano, R., Hinojosa Reyes, L., Hernandez-Ramirez, A., & Acuna-Askar, K. Journal of the Chilean Chemical Society, 2010, 55(4), 486-490.
[25] Trasande, L., Cortes, J. E., Landrigan, P. J., Abercrombie, M. I., Bopp, R. F., & Cifuentes, E. Environmental Health, 2010, 9(1),
[26] Páez-Osuna, F., Calderón-Campuzano, M. F., Soto-Jiménez, M. F., & Ruelas-Inzunza, J. Marine pollution bulletin, 2011, 62(6), 1320-1323.
[27] Evan P. Beaumier , Brennan S. Billow , Amrendra K. Singh , Shannon M. Biros and Aaron L. Odom Chem. Sci., 2016, 7, 2532-2536
[28] Jie Liu, Yuan-Ye Bao, Ye Liu, Wei-Min Ren, Xiao-Bing Lu, Polym. Chem., 2013, 4, 1439-1444
[29] Guo, B. L.-J.-G.-P.-Y. Inorganica Chimica Acta, 2012, 392, 4987-4994.
[30] Bao-Lin Liu, Yan-Xia Wang, Fan-Hong Kong, Ruo-Jie Tao, Inorganica Chimica Acta, 2012, 392,469–472
[31] Kusaï Alomar, Vincent Gaumet, Magali Allain, Pascal Richomme, Gilles Bouet, Inorganica Chimica Acta, 2012, 433–439
[32] CONAGUA, Norma Mexicana NMX-AA-044-SCFI-2014 Análisis de agua, medición de cromo hexavalente en aguas naturales, salinas residuales y residuales tratadas-Método de Prueba, 2014.
[33]Vargas-Nieto C., Carriazo J.G., Castillo E., Ing. Investig, 2011, 31,154-162.
[34]Glorias-García F., Arriaga-Merced J.M., Roa-Morales G., Varela-Guerrero V., Barrera-Díaz C.E., Bilveu B., Journal on Industrial and Engineering Chemestry, 2014, 20, 2477-2483
Published
2016-09-30
How to Cite
Tovar-Corona, A., Vázquez-Cuchillo, O., Moreno-Luna, F., & Hernández-Tosca, D. (2016). Biotechnological system for the reduction of chromium (VI) in wastewater. Tópicos De Investigación En Ciencias De La Tierra Y Materiales, 3(3), 163-174. https://doi.org/10.29057/aactm.v3i3.9627
Section
Articles
