Synthesis and characterization of nickel ferrites obtained by the combustion method
Keywords:
Characterization, Synthesis, Ferrites
Abstract
NiFe₂O₄ ceramic powders were synthesized by the combustion route, using citric acid as fuel. The precursors used were Ni(NO₃)₂.6H2O and Fe(NO₃)₃.9H2O. The synthesis was carried out at an average temperature of 600°C in an air atmosphere, developing the reaction in approximately 15 minutes. Subsequently, a heat treatment was applied at 1000°C for 8 hours in an air atmosphere. The phase analysis was performed by means of X-ray diffraction. They are also characterized by scanning electron microscopy and a semi-quantitative chemical analysis is applied. The results indicate having obtained a single NiFe2O4 phase. The magnetism of the powders was verified, obtaining an excellent magnetic response for the sample subjected to heat treatment.
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References
1. E. R. Camargo. “Estudio comparativo de algunas ferritas obtenidas por el método citrato”. Diss. Universidad Nacional de Colombia, 2011.
2. F. Prieto, R. Rivera, M. Méndez & M. Gordillo, “Caracterización de ferritas de níquel obtenidas mediante mecanosíntesis”. RLMM, vol. 28, 2, 2008, pp.111-120.
3. S. S. Chauhan, C. Ojha, , & A. K. Shrivastava, “Synthesis and characterization of CuFe2O4” J Theo App Sci, vol.1, 2, 2009, pp. 91-11.
4. W. Pan, F. Gu, K. Qi, Q. Liu & J. Wang, “Effect of Zn substitution on morphology and magnetic properties of copper ferrite nanofibers” preprint 2011, 1106.1269.
5. D. Thapa, N. Kulkarni, S. N. Mishra, P. L. Paulose, & P. Ayyub, “Enhanced magnetization in cubic ferrimagnetic CuFe2O4 nanoparticles synthesized from a citrate precursor: the role of Fe2+”. J Phys D: App Phy, Vol. 43, 19, 2010, pp 195004.
6. S. Tao, F. Gao, X. Liu, & O. Toft Sorensen, “Preparation and gas-sensing properties of CuFe2O4 at reduced temperature”, Mat Sci Eng.: B, vol.77, 2, 2000, pp. 172-176.
7. Z. Xiao, S. Jin, X. Wang, W. Li, J. Wang & C. Liang, “Preparation, structure and catalytic properties of magnetically separable Cu–Fe catalysts for glycerol hydrogenolysis”, J Mat Chem, vol. 22, 32, 2012, 16598-16605.
8. G. F. Goya, H. R. Rechenberg & J. Z. Jiang, “Structural and magnetic properties of ball milled copper ferrite”. J app phy., vol. 84, 2, 1998 pp. 1101-1108.
9. J. Z., Goya, G. F., & Rechenberg, H. R. “Magnetic properties of nanostructured CuFe2O4”. Journal of Physics: Condensed Matter, vol. 11, 20, 1999, pp. 4063.
10. M. Ristić, B. Hannoyer, S. Popović, S. Musić & N. Bajraktaraj, Ferritization of copper ions in the Cu–Fe–O system. Mat. Sci. Eng.: B, vol. 77, 1, 2000, pp. 73-82.
11. B. S. Randhawa, H. S. Dosanjh & M. Kaur, “Preparation of ferrites from the combustion of metal nitrate-oxalyl dihydrazide solutions”. Ind. J. Eng. Mater. Sci, vol. 12, 2005, pp. 151-154.
12. K. C. Patil, S. T. Aruna, & T. Mimani, “Combustion synthesis: an update”, Current Opinion in Solid State and Materials Science, vol. 6, 6, pp. 507-512.
13. Y. Zhang, & G. C. Stangle, “Preparation of fine multicomponent oxide ceramic powder by a combustion synthesis process” J Mat Res, vol. 9, 8, 1994, pp. 1997-2004.
14. F. L. García, L. E. Hernández Cruz, F. J. García Delgado, A. M. Bolarín Miró, & F. Sánchez de Jesús, “Comparative study of the use of citric acid and urea in the synthesis of calcium manganites doped with Eu, by combustion method”, Revista Latinoamericana de Metalurgia y Materiales, 2011, pp. 12-20.
15. F. L. García, V. G. D Resende, E. De Grave, A. Peigney, A. Barnabé & C. Laurent, “Ironstabilized nanocrystalline ZrO2 solid solutions: Synthesis by combustion and thermal stability”. Mat. Res. Bull., vol. 44, 6, 2009, pp. 1301-1311.
16. F. L. García, A. Peigney, A. & C. Laurent, “Tetragonal-(Zr, Co) O2 solid solution: Combustion synthesis, thermal stability in air and reduction in H2, H2-CH4 and H2-C2H4 atmospheres”,
Materials Research Bulletin, vol. 43, 11, 2008, pp. 3088-3099.
2. F. Prieto, R. Rivera, M. Méndez & M. Gordillo, “Caracterización de ferritas de níquel obtenidas mediante mecanosíntesis”. RLMM, vol. 28, 2, 2008, pp.111-120.
3. S. S. Chauhan, C. Ojha, , & A. K. Shrivastava, “Synthesis and characterization of CuFe2O4” J Theo App Sci, vol.1, 2, 2009, pp. 91-11.
4. W. Pan, F. Gu, K. Qi, Q. Liu & J. Wang, “Effect of Zn substitution on morphology and magnetic properties of copper ferrite nanofibers” preprint 2011, 1106.1269.
5. D. Thapa, N. Kulkarni, S. N. Mishra, P. L. Paulose, & P. Ayyub, “Enhanced magnetization in cubic ferrimagnetic CuFe2O4 nanoparticles synthesized from a citrate precursor: the role of Fe2+”. J Phys D: App Phy, Vol. 43, 19, 2010, pp 195004.
6. S. Tao, F. Gao, X. Liu, & O. Toft Sorensen, “Preparation and gas-sensing properties of CuFe2O4 at reduced temperature”, Mat Sci Eng.: B, vol.77, 2, 2000, pp. 172-176.
7. Z. Xiao, S. Jin, X. Wang, W. Li, J. Wang & C. Liang, “Preparation, structure and catalytic properties of magnetically separable Cu–Fe catalysts for glycerol hydrogenolysis”, J Mat Chem, vol. 22, 32, 2012, 16598-16605.
8. G. F. Goya, H. R. Rechenberg & J. Z. Jiang, “Structural and magnetic properties of ball milled copper ferrite”. J app phy., vol. 84, 2, 1998 pp. 1101-1108.
9. J. Z., Goya, G. F., & Rechenberg, H. R. “Magnetic properties of nanostructured CuFe2O4”. Journal of Physics: Condensed Matter, vol. 11, 20, 1999, pp. 4063.
10. M. Ristić, B. Hannoyer, S. Popović, S. Musić & N. Bajraktaraj, Ferritization of copper ions in the Cu–Fe–O system. Mat. Sci. Eng.: B, vol. 77, 1, 2000, pp. 73-82.
11. B. S. Randhawa, H. S. Dosanjh & M. Kaur, “Preparation of ferrites from the combustion of metal nitrate-oxalyl dihydrazide solutions”. Ind. J. Eng. Mater. Sci, vol. 12, 2005, pp. 151-154.
12. K. C. Patil, S. T. Aruna, & T. Mimani, “Combustion synthesis: an update”, Current Opinion in Solid State and Materials Science, vol. 6, 6, pp. 507-512.
13. Y. Zhang, & G. C. Stangle, “Preparation of fine multicomponent oxide ceramic powder by a combustion synthesis process” J Mat Res, vol. 9, 8, 1994, pp. 1997-2004.
14. F. L. García, L. E. Hernández Cruz, F. J. García Delgado, A. M. Bolarín Miró, & F. Sánchez de Jesús, “Comparative study of the use of citric acid and urea in the synthesis of calcium manganites doped with Eu, by combustion method”, Revista Latinoamericana de Metalurgia y Materiales, 2011, pp. 12-20.
15. F. L. García, V. G. D Resende, E. De Grave, A. Peigney, A. Barnabé & C. Laurent, “Ironstabilized nanocrystalline ZrO2 solid solutions: Synthesis by combustion and thermal stability”. Mat. Res. Bull., vol. 44, 6, 2009, pp. 1301-1311.
16. F. L. García, A. Peigney, A. & C. Laurent, “Tetragonal-(Zr, Co) O2 solid solution: Combustion synthesis, thermal stability in air and reduction in H2, H2-CH4 and H2-C2H4 atmospheres”,
Materials Research Bulletin, vol. 43, 11, 2008, pp. 3088-3099.
Published
2014-09-01
How to Cite
Maya-Dorantes, C., Legorreta-García , F., & Arenas-Flores, A. (2014). Synthesis and characterization of nickel ferrites obtained by the combustion method. Tópicos De Investigación En Ciencias De La Tierra Y Materiales, 1(1), 126-133. https://doi.org/10.29057/aactm.v1i1.9945
Section
Articles
