Extracción de ibuprofeno empleando dicarboxilato de celulosa nanocristalina
Resumen
La celulosa al reaccionar con periodato de sodio se oxida parcialmente produciendo un dialdehído que se conoce en inglés como “hairy cellulose”. Este tipo de celulosa se compone de un cuerpo cristalino, que proporciona resistencia fisicoquímica, y cadenas de celulosa amorfas en los extremos las cuales tienen disposición para ser modificadas químicamente. Una de estas modificaciones se realiza con clorito de sodio el cual oxida selectivamente a aldehídos produciendo el dicarboxilato de celulosa nanocristalina (DCCN), este material con gran carga electrostática se ha empleado principalmente para la extracción de metales y en menor proporción para compuestos orgánicos. Por esta razón, en este trabajo se empleó como sorbente en la preconcentración de ibuprofeno. Se evaluaron diferentes condiciones como pH, concentración inicial, masa del sorbente y la presencia de otros fármacos (naproxeno y diclofenaco). A pH 7 empleando 10 mg del DCCN se logró retener más del 80% del fármaco en solución acuosa y una capacidad máxima de 176.7 mg·g-1.
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Derechos de autor 2023 Tanese Montesinos-Vázquez, Susana Rojas-Lima, José Antonio Rodríguez-Ávila, Carlos Andrés Galán-Vidal, Jessica Acuña-Nicolás, María Elena Páez-Hernández
Esta obra está bajo licencia internacional Creative Commons Reconocimiento-NoComercial-SinObrasDerivadas 4.0.
