Condiciones óptimas para sintetizar carbón conductor en atmósfera de aire
Resumen
Este documento describe el procedimiento para encontrar las condiciones óptimas de carbonización de cáscara de naranja (CN) en atmósfera de aire. Las condiciones de carbonización fueron simuladas mediante análisis de elementos finitos en el software ANSYS Mechanical, variando temperaturas (600, 700, 800, 900 y 1000°C), tamaños de cámara de mufla, tipo de resistencia del horno y número de arreglos en el proceso. Se realizó análisis termogravimétrico (TGA) mostrando que la que CN en contacto con el aire, se consume en un 99% a los 600°C. La medición de resistencia mostró que las muestras más conductoras fueron las sometidas a 1000°C en la mufla. La voltametría cíclica (VC) proporcionó el valor de la capacitancia de los carbones. Siendo el valor máximo 272 F/g encontrado en las muestras sometidas en una mufla de resistencia de cilíndrica con dos arreglos dentro. Los valores de capacitancia obtenidos para estos carbones, los colocan dentro del rango de capacitancias manejadas en la literatura para aplicaciones de electrodos de supercapacitores.
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Ahmed, S., Rafat, M., & Ahmed, A. (2018). Nitrogen doped activated carbon derived from orange peel for supercapacitor application. Advances in Natural Sciences: Nanoscience and Nanotechnology, 9(3). https://doi.org/10.1088/2043-6254/aad5d4
Arias-Niquepa, R. A., Prías-Barragán, J. J., Ariza-Calderón, H., & Rodríguez-García, M. E. (2019). Activated Carbon Obtained from Bamboo: Synthesis, Morphological, Vibrational, and Electrical Properties and Possible Temperature Sensor. Physica Status Solidi (A) Applications and Materials Science, 216(4), 1–11. https://doi.org/10.1002/pssa.201800422
Babu, B. V., & Chaurasia, A. S. (2004). Pyrolysis of biomass: Improved models for simultaneous kinetics and transport of heat, mass and momentum. Energy Conversion and Management, 45(9–10), 1297–1327. https://doi.org/10.1016/j.enconman.2003.09.013
Brito, G. M., Cipriano, D. F., Schettino, M. Â., Cunha, A. G., Coelho, E. R. C., & Checon Freitas, J. C. (2019). One-step methodology for preparing physically activated biocarbons from agricultural biomass waste. Journal of Environmental Chemical Engineering, 7(3), 103113. https://doi.org/10.1016/j.jece.2019.103113
Choi, N. S., Chen, Z., Freunberger, S. A., Ji, X., Sun, Y. K., Amine, K., Yushin, G., Nazar, L. F., Cho, J., & Bruce, P. G. (2012). Challenges facing lithium batteries and electrical double-layer capacitors. Angewandte Chemie - International Edition, 51(40), 9994–10024. https://doi.org/10.1002/anie.201201429
Dujearic-Stephane, K., Panta, P., Shulga, Y. M., Kumar, A., Gupta, M., & Kumar, Y. (2020). Physico-chemical characterization of activated carbon synthesized from Datura metel’s peels and comparative capacitive performance analysis in acidic electrolytes and ionic liquids. Bioresource Technology Reports, 100516. https://doi.org/10.1016/j.biteb.2020.100516
Edy, D. L., & Widiyanti. (2020). Analysis of heat load in coffee bean drying oven room. Journal of Physics: Conference Series, 1700(1). https://doi.org/10.1088/1742-6596/1700/1/012036
García, R., Pizarro, C., Lavín, A.G. & Bueno, J.L., (2013). Biomass Proximate Analysis using Thermogravimetry, Bioresource Technology doi: http://dx.doi.org/10.1016/j.biortech.2013.03.197
Gualous, H., Bouquain, D., Berthon, A., & Kauffmann, J. M. (2003). Experimental study of supercapacitor serial resistance and capacitance variations with temperature. Journal of Power Sources, 123(1), 86–93. https://doi.org/10.1016/S0378-7753(03)00527-5
Gunasekaran, S. S., & Badhulika, S. (2022). Effect of pH and activation on macroporous carbon derived from cocoa-pods for high performance aqueous supercapacitor application. Materials Chemistry and Physics, 276,125399. https://doi.org/10.1016/J.MATCHEMPHYS.2021.125399
Hesas, R. H., Arami-Niya, A., Ashri, W. M., Daud, W., & Sahu, J. N. (2013). Preparation and Characterization of Activated Carbon from Apple Waste by Microwave-Assisted Phosphoric Acid Activation: Application in Methylene Blue Adsorption. Bioresources, 8(2), 2950-2966. DOI: 10.15376/biores.8.2.2950-2966
Kaipannan, S., & Marappan, S. (2019). Fabrication of 9.6 V High-performance Asymmetric Supercapacitors Stack Based on Nickel Hexacyanoferrate-derived Ni(OH)2 Nanosheets and Bio-derived Activated Carbon. Scientific Reports, 9(1), 1–15. https://doi.org/10.1038/s41598-018-37566-8
Krupka, J., & Strupinski, W. (2010). Measurements of the sheet resistance and conductivity of thin epitaxial graphene and SiC films. Applied Physics Letters, 96(8). https://doi.org/10.1063/1.3327334
Li, X. R., Jiang, Y. H., Wang, P. Z., Mo, Y., Lai, W. De, Li, Z. J., Yu, R. J., Du, Y. T., Zhang, X. R., & Chen, Y. (2020). Effect of the oxygen functional groups of activated carbon on its electrochemical performance for supercapacitors. New Carbon Materials, 35(3), 232–243. https://doi.org/10.1016/S1872-5805(20)60487-5
Meenatchi, T., Priyanka, V., Subadevi, R., Liu, W. R., Huang, C. H., & Sivakumar, M. (2021). Probe on hard carbon electrode derived from orange peel for energy storage application. Carbon Letters, 31(5), 1033–1039. https://doi.org/10.1007/s42823-020-00217-y
Merlet, C., Rotenberg, B., Madden, P. A., Taberna, P. L., Simon, P., Gogotsi, Y., & Salanne, M. (2012). On the molecular origin of supercapacitance in nanoporous carbon electrodes. Nature Materials, 11(4), 306–310. https://doi.org/10.1038/nmat3260
Miranda, R., Bustos-Martinez, D., Blanco, C. S., Villarreal, M. H. G., & Cantú, M. E. R. (2009). Pyrolysis of sweet orange (Citrus sinensis) dry peel. Journal of Analytical and Applied Pyrolysis, 86(2), 245–251. https://doi.org/10.1016/j.jaap.2009.06.001
Pichler, M., Haddadi, B., Jordan, C., Norouzi, H., & Harasek, M. (2021). Influence of particle residence time distribution on the biomass pyrolysis in a rotary kiln. Journal of Analytical and Applied Pyrolysis, 158. https://doi.org/10.1016/j.jaap.2021.105171
Portet, C., Taberna, P. L., Simon, P., Flahaut, E., & Laberty-Robert, C. (2005). High power density electrodes for Carbon supercapacitor applications. Electrochimica Acta, 50(20), 4174–4181. https://doi.org/10.1016/j.electacta.2005.01.038
Raghu, M. S., Parashuram, L., Yogesh Kumar, K., Prasanna, B. P., Rao, S., Krishnaiah, P., Prashanth, K. N., Pradeep Kumar, C. B., & Alrobei, H. (2020). Facile green synthesis of boroncarbonitride using orange peel; Its application in high-performance supercapacitors and detection of levodopa in real samples. Materials Today Comunications, 24(1), 1–8. https://doi.org/10.1016/j.mtcomm.2020.101033
Saini, S., Chand, P., & Joshi, A. (2021). Biomass derived carbon for supercapacitor applications : Review. Journal of Energy Storage, 39, 102646. https://doi.org/10.1016/j.est.2021.102646
Shanmuga Priya, M., Divya, P., & Rajalakshmi, R. (2020). A review status on characterization and electrochemical behaviour of biomass derived carbon materials for energy storage supercapacitors. Sustainable Chemistry and Pharmacy, 16, 100243. https://doi.org/10.1016/j.scp.2020.100243
Sheng, Z., Lin, X., Wei, H., Zhang, Y., Tian, Z., Wang, C., Xu, D., & Wang, Y. (2021). Green synthesis of nitrogen-doped hierarchical porous carbon nanosheets derived from polyvinyl chloride towards high-performance supercapacitor. Journal of Power Sources, 515, 230629. https://doi.org/10.1016/J.JPOWSOUR.2021.230629
Shi, B., Xu, L., Zhang, J., Meng, J., Wang, X., Bu, C., & Liu, C. (2022). Template-assisted synthesis of nitrogen-doped porous carbon derived from bean dregs for high-performance supercapacitor. Asia-Pacific Journal of Chemical Engineering, 17(4), e2802. https://doi.org/10.1002/APJ.2802
Súarez-Velázquez, G. G., Pech-Rodríguez W. J., Ramírez de León, J. A., Castañón-Rodríguez J. F., Meléndez-González, P. C. & Galaviz-Pérez J. A. (2022) Orange peel as substrate to synthesize conductive carbon nanostructures by a green thermal process, Revista Internacional de Contaminación Ambiental, 38, 34–47, [Online]. https://doi.org/10.20937/RICA.54242
Súarez-Velázquez, G. G., J. A. Ramírez de León, J. F. Castañón-Rodríguez, J. A. Galavíz-Pérez, and P. C. Meléndez-González. 2021. Valorization of Albedo Orange Peel Waste to Develop Electrode Materials in Supercapacitors for the Electric Industry. 2021, 3022815. https://doi.org/10.1155/2021/3022815
Xie, K., Xia, K., Ding, X., Fang, L., Liu, X., & Zhang, X. (2022). Facile preparation of 3D porous agar-based heteroatom-doped carbon aerogels for high-energy density supercapacitors. RSC Advances, 12 (32), 20975–20982. https://doi.org/10.1039/d2ra03685a
Xu, C., Hu, Z., Wang, X., Wang, C., Huang, D., & Qian, Y. (2021). Facile Preparation of Hierarchical Porous Carbon from Orange Peels for High-Performance Supercapacitor. Int. J. Electrochem. Sci., 16. https://doi.org/10.20964/2021.03.07
Yu, J., Wu, J., Yang, Z., Cai, J., & Zhang, Z. (2020). A cheese-shaped bio-carbon for high performance supercapacitors prepared from Juncus effuses. L. Journal of Energy Storage, 30, 1–7. https://doi.org/10.1016/j.est.2020.101531
Zhang, L. L., and Zhao, X. S. (2009). Carbon-based materials as supercapacitor electrodes. Chemical Society Reviews, 38(9), 2520–2531. https://doi.org/10.1039/b813846j
Derechos de autor 2023 Gladis Guadalupe Suárez-Velázquez, Ernesto Cuahutemóc Herbert-López, María Guadalupe Burgos-Quiroz
Esta obra está bajo licencia internacional Creative Commons Reconocimiento-NoComercial-SinObrasDerivadas 4.0.