Determinación espectrofotométrica de Nd(III) en sistemas acuosos bifásicos

Palabras clave: neodimio, ligante, polietilénglicol, sal, sistemas, acuosos, bifásicos

Resumen

En este trabajo se evaluó la determinación espectrofotométrica de Nd(III) usando el 4-(2-piridilazo)resorcinol (PAR) como ligante y su aplicación a un sistema acuoso bifásico (polímero-sal). Se analizó el efecto que tiene la relación metal:ligando, presencia de sal (Na2SO4) y polímero (polietilenglicol) en la determinación de Nd(III). Una vez definidas las condiciones de medición, se evalúo extracción de Nd(III) en un sistema de sistema acuoso bifásico compuesto por 20% p/p Na2SO4/H2O y PEG-1000/H2O al 35% p/p en diferentes condiciones de acidez: sin ácido, 0.1 mol L-1 HCl y 0.1 mol L-1 H2SO4.

Descargas

La descarga de datos todavía no está disponible.

Citas

Alguacil, F. J., & Rodríguez, F. (1997). Separation processes in rare earths. Revista de Metalurgia, 33(3 SE-Reviews), 187–196. Retrieved from https://revistademetalurgia.revistas.csic.es/index.php/revistademetalurgia/article/view/862

Balaram, V. (2019). Rare earth elements: A review of applications, occurrence, exploration, analysis, recycling, and environmental impact. Geoscience Frontiers, 10(4), 1285–1303. Retrieved from https://www.sciencedirect.com/science/article/pii/S1674987119300258

Contreras Camarillo, Y. C., Cruz Rico, V. G., Moya Contreras, N. D., Prieto Manjarrez, L. G., Ramírez Sagaón, D. M., Robles Aguirre, L. M., Martínez Rodríguez, D. E., et al. (2021). Sistemas de Extracción Sustentables para la Recuperación de Iones Metálicos y Fármacos. JÓVENES EN LA CIENCIA, 10(SE-). Retrieved from https://www.jovenesenlaciencia.ugto.mx/index.php/jovenesenlaciencia/article/view/3335

Elmer, P. (1996) Atomic Absorption Spectroscopy: Analytical Methods. The Perkin Elmer Corporation, Waltham.

Gielen, D. and M. Lyons (2022), Critical materials for the energy transition: Lithium, International Renewable Energy Agency, Abu Dhabi. ISBN 978-92-9260-418-9

Goueguel, C., McIntyre, D. L., Jain, J., Karamalidis, A. K., & Carson, C. (2015). Matrix effect of sodium compounds on the determination of metal ions in aqueous solutions by underwater laser-induced breakdown spectroscopy. Applied Optics, 54(19), 6071–6079. Optica Publishing Group. Retrieved from https://opg.optica.org/ao/abstract.cfm?URI=ao-54-19-6071

Greenwood, N, N., & Earnshaw, A. (1997). The Lanthanide Elements (Z = 58–71). Chemistry of the Elements (Second Ed., pp. 1227–1249). Oxford: Butterworth-Heinemann. Retrieved from: https://www.sciencedirect.com/science/article/pii/B9780750633659500365

Grilo, A. L., Raquel Aires-Barros, M., & Azevedo, A. M. (2016). Partitioning in Aqueous Two-Phase Systems: Fundamentals, Applications and Trends. Separation & Purification Reviews, 45(1), 68–80. Taylor & Francis. Retrieved from https://doi.org/10.1080/15422119.2014.983128

Haque, N., Hughes, A., Lim, S., & Vernon, C. (2014). Rare Earth Elements: Overview of Mining, Mineralogy, Uses, Sustainability and Environmental Impact. Resources, 3, 614-635. DOI: 10.3390/resources3040614

Hirosawa, S., & Hono, K. (2022). Foreword to the Focus Issue: science and technology of element-strategic permanent magnets. Science and Technology of Advanced Materials, 23(1), 64–65. Taylor & Francis. Retrieved from https://doi.org/10.1080/14686996.2022.2027641

Iqbal, M., Tao, Y., Xie, S., Zhu, Y., Chen, D., Wang, X., Huang, L., et al. (2016). Aqueous two-phase system (ATPS): an overview and advances in its applications. Biological Procedures Online, 18(1), 18. Retrieved from https://doi.org/10.1186/s12575-016-0048-8

Karipcin, F., & Kabalcilar, E. (2007). Spectroscopic and Thermal Studies on Solid Complexes of 4-(2-pyridylazo) resorcinol with Some Transition Metals. Acta Chimica Slovenica, 54(2).

Munshi, K. N., & Dey, A. K. (1964). Spectrophotometric Determination of Rare Earth Metals with 4-(2-Pyridylazo)resorcinol. Analytical Chemistry, 36(10), 2003–2004. American Chemical Society. Retrieved from https://doi.org/10.1021/ac60216a037

Murthy, Z. V. P., & Choudhary, A. (2011). Application of nanofiltration to treat rare earth element (neodymium) containing water. Journal of Rare Earths, 29(10), 974–978. Retrieved from https://www.sciencedirect.com/science/article/pii/S1002072110605819

Ohyoshi, E. (1984). Spectrophotometric determination of formation constants of 1:1 complexes of lanthanides with 4-(2-pyridylazo)resorcinol (par). Talanta, 31(12), 1129–1132. Retrieved from https://www.sciencedirect.com/science/article/pii/0039914084802647

Omodara, L., Pitkäaho, S., Turpeinen, E.-M., Saavalainen, P., Oravisjärvi, K., & Keiski, R. L. (2019). Recycling and substitution of light rare earth elements, cerium, lanthanum, neodymium, and praseodymium from end-of-life applications - A review. Journal of Cleaner Production, 236, 117573. Retrieved from https://www.sciencedirect.com/science/article/pii/S095965261932387X

Regadío, M., Riaño, S., Binnemans, K., & Vander Hoogerstraete, T. (2017). Direct Analysis of Metal Ions in Solutions with High Salt Concentrations by Total Reflection X-ray Fluorescence. Analytical Chemistry, 89(8), 4595–4603. American Chemical Society. Retrieved from https://doi.org/10.1021/acs.analchem.7b00097

Romero, X., Poussel, E., & Mermet, J. M. (1997). The effect of sodium on analyte ionic line intensities in inductively coupled plasma atomic emission spectrometry: influence of the operating conditions. Spectrochimica Acta Part B: Atomic Spectroscopy, 52(4), 495–502. Retrieved from: https://www.sciencedirect.com/science/article/pii/S0584854796016011

Skoog, Douglas A., Donald M. West, F. James Holler, and Crouch, S. R. (2015). Fundamentos De Química Analítica (9a. Edición). Cengage Learning. México, D.F.

Sprecher, B., Kleijn, R., & Kramer, G. J. (2014). Recycling Potential of Neodymium: The Case of Computer Hard Disk Drives. Environmental Science & Technology, 48(16), 9506–9513. American Chemical Society. Retrieved from https://doi.org/10.1021/es501572z

Publicado
2023-04-28
Cómo citar
Vázquez-Navarro, N. G., Navarro-Segura, D. L., Cholico-González, D. F., & Ávila-Rodríguez, M. (2023). Determinación espectrofotométrica de Nd(III) en sistemas acuosos bifásicos. Pädi Boletín Científico De Ciencias Básicas E Ingenierías Del ICBI, 11(Especial), 58-63. https://doi.org/10.29057/icbi.v11iEspecial.10388