Análisis de fases zeolíticas del sistema Na2O-Al2O3-SiO2-H2O obtenidas por hidrólisis alcalina isotérmica de caolín
Resumen
Bajo la premisa de que la permineralización inducida por sílice durante la formación de fósiles silicatados comporta la estabilización de fases intermedias de estructura zeolítica, planteamos la reproducción de este proceso natural mediante la síntesis de materiales zeolíticos en un sistema reactivo hidrotermal isotérmico (140 ºC), con NaOH, a partir de caolín como fuente de aluminosilicato. El resultado es la obtención de diversas mezclas de las fases hidroxicancrinita, hidroxisodalita, zeolita tipo NaP 1 y analcima, en un rango de tiempo de reacción que va de 7 a 9 horas. El análisis de estas mezclas se ha llevado a cabo mediante difracción de Rayos-X en muestra polvo y representa una guía útil para identificar mezclas complejas de estructuras zeolíticas sódicas, reportando tablas (hkl)/dhkl para cada una de las fases. El estudio incorpora dos hallazgos inéditos: i) la transición de fase de hidroxisodalita a hidroxicancrinita se muestra por primera vez en condiciones isotérmicas sin carbonatos, y ii) la elucidación del grupo de simetría espacial para la hidroxisodalita da como resultado el grupo cúbico quiral P4332 (o P4132).
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Derechos de autor 2024 Erick Abiel Rodríguez-Benítez, Carlos Esquivel-Macías, Félix Sánchez-De Jesús, Ana María Bolarín-Miró, Julio Cesar Juárez-Tapia, Marius Ramirez-Cardona
Esta obra está bajo licencia internacional Creative Commons Reconocimiento-NoComercial-SinObrasDerivadas 4.0.
