Influencia del disolvente en la elaboración de una membrana polimérica de inclusión (PIM)
Resumen
En el siguiente trabajo se evaluó la influencia que presenta el cambio de disolvente empleado en la formación de una membrana polimérica de inclusión (PIM) sobre su morfología y propiedades mecánicas. Los componentes de la PIM empleados fueron: poliestireno expandido recuperado (Pst) como soporte polimérico, aliquat 336 como agente extractante y 2- nitrofeniloctiléter como plastificante. Las membranas elaboradas fueron caracterizadas mediante ángulo de contacto, porosidad, microscopia electrónica de barrido y la extracción en batch del ácido acetilsalicílico presente en una solución acuosa observándose que es posible eliminarlo hasta en un 83.90%. Todo esto permite ver que la membrana desarrollada puede ser utilizada para el tratamiento de contaminantes emergentes y la disminución de plásticos de un solo uso.
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Ahmad, T., Guria, C., & Mandal, A. (2018). Synthesis, characterization and performance studies of mixed-matrix poly (vinyl chloride)-bentonite ultrafiltration membrane for the treatment of saline oily wastewater. Process Safety and Environmental Protection, 116, 703-717. DOI:10.1016/j.psep.2018.03.033
Fontàs C., Tayeb R., Dhahbi M., Gaudichet E., Thominette F., Roy P., Steenkeste K., Pierre M., Tingry S., Tronel-Peyroz E., Seta P., (2007). Polymer inclusion membranes: The concept of fixed sites membrane revised. Journal of Membrane Science 290, 62-72. DOI:10.1016/j.memsci.2006.12.019.
Garcia-Rodríguez, A., Matamoros, V., Kolev, S. D., & Fontàs, C. (2015). Development of a polymer inclusion membrane (PIM) for the preconcentration of antibiotics in environmental water samples. Journal of membrane science, 492, 32-39. DOI:10.1016/j.memsci.2015.05.037
Gherasim C. V., Cristea, M. G., Vasile C. B., (2011). New polymer inclusion membrane. Preparation and characterization. Digest Journal of Nanomaterials and Biostructures 6(4).
Giuliani F., Autelitano F., Garilli E., Montepara A., (2020). Expanded polystyrene (EPS) in road construction: Twenty years of Italian experiences. Transportation Research Procedia 45, 410-417. DOI:10.1016/j.trpro.2020.03.033.
Jayawardane B. M., Cattrall R. W., Kolev D. S., (2013). The use of a polymer inclusion membrane in a paper-based sensor for the selective determination of Cu(II). Analytica Chimica Acta 803, 106-112. DOI:10.1016/j.aca.2013.07.029
Jha R., Rao M.D., Meshram A., Verma H. R, Singh K. K., (2020). Potential of polymer inclusion membrane process for selective recovery of metal values from waste printed circuit boards: A review. Journal of Cleaner Production 265. DOI:10.1016/j.jclepro.2020.121621
Jin T., Zhao Z., Chen K., (2015). Preparation of a poly(vinyl chloride) ultrafiltration membrane through the combination of thermally induced phase separation and non‐solvent‐induced phase separation. Journal Of Applied Polymer Science 133 (5). DOI:10.1002/app.42953
Kazemzadeh H., Karimi-Sabet J., Towfighi J., Adhami A., (2020). Evaluation of polymer inclusion membrane efficiency in selective separation of lithium ion from aqueous solution. Separation and Purification Technology 251, 117298. DOI:10.1016/j.seppur.2020.117298
Kebiche-Senhadji O., Tingry S., Seta P., Benamor M., (2010). Selective extraction of Cr(VI) over metallic species by polymer inclusion membrane (PIM) using anion (Aliquat 336) as carrier. Desalination, 258(1-3), 59-65. DOI: 10.1016/j.desal.2010.03.047
Keskin B., Zeytuncu-Gökoğlu B., Koyuncu I., (2021). Polymer inclusion membrane applications for transport of metal ions: A critical review. Chemosphere 279, 130604. DOI: 10.1016/j.chemosphere.2021.130604
Kunene P., Akinbami O., Motsoane N., Tutu H., Chimuka L., Richards H., (2020). Feasibility of polysulfone as base polymer in a polymer inclusion membrane: Synthesis and characterisation. Journal of Membrane Science and Research 6(2), 203-210. DOI: 10.22079/JMSR.2019.111596.1278
Laviana O., (2020). Determinación experimental de la constante de formación del complejo Fe(III)-salicilato. Grado en química universidad de Olaya.
Lemus-Solorio A., Núñez-Gaytán M. E., Núñez-Gaytán A. M., Lemus-Solorio M. A., Núñez-Hernández S., (2021). Separación de metales en soluciones acuosas mediante membranas poliméricas con extractantes novedosos. Revista de Ciencias Tecnológicas 4, 99-111.
Ling, Y. Y., & Suah M. (2017). Extraction of malachite green from wastewater by using polymer inclusion membrane. Journal of Environmental Chemical Engineering, 5(1) 785-794. DOI:10.1016/j.jece.2017.01.001
Martínez, L. P. (1999). Caracterización estructural y superficial. Universidad Valladolid. Valladolid Miguel de Cervantes. DOI: 10.35376/10324/67
Nghiem L.D., Mornane P., Potter I. D., Perera J. M., Cattrall R. W., Kolev S. D., (2006). Extraction and transport of metal ions and small organic compounds using polymer inclusion membranes (PIMs). Journal of Membrane Science 281(1-2), 7-41. DOI:10.1016/j.memsci.2006.03.035.
Noble, R. D., (1987). Membrane Contactors and Integrated Membrane Operations. Separation Science and Technology 22, 2-3. 731-743.
Nunes S. P., Culfaz-Emecen, P. Z., Guy Z. R., Visser T., Koops G. H., Wanqin J.,Ulbricht M., (2020). Thinking the future of membranes: Perspectives for advanced and new membrane materials and manufacturing processes. Journal of Membrane Science 598, 117761. DOI:10.1016/j.memsci.2019.117761
Obotey, E. E., Rathilal, S. (2020). Membrane technologies in wastewater treatment: a review. Membranas 10(5), 89. DOI:10.3390/membranes10050089.
Pereira N., John A., Cattrall R. W., Perera J. M., Kolev, S. D., (2009). Influence of the composition of polymer inclusion membranes on their homogeneity and flexibility. Desalination, 236(1-3), 327-333. DOI:10.1016/j.desal.2007.10.083
Piotr S., Haopeng G., Krzysztof D., Zbigniew R., Andrzej W., Kateryna F., Joanna K., Wojciech K., (2021). New reactive ionic liquids as carriers in polymer inclusion membranes for transport and separation of Cd(II), Cu(II), Pb(II), and Zn(II) ions from chloride aqueous solutions. Journal of Membrane Science 638, 119674. DOI:10.1016/j.memsci.2021.119674
Radzyminska-Lenarcik, E., Maslowska, K., & Urbaniak, W. (2021). Removal of copper (II), zinc (II), cobalt (II), and nickel (II) ions by PIMs doped 2-Alkylimidazoles. Membranes, 12(1), 16. DOI: 10.3390/membranes12010016
Sellami F., Kebiche-Senhadj O., Marais S., Colasse L., Fatyeyeva K., (2020). Enhanced removal of Cr(VI) by polymer inclusion membrane based on poly(vinylidene fluoride) and Aliquat 336. Separation and Purification Technology 248, 117038. DOI:10.1016/j.seppur.2020.117038
Sellami F., Kebiche-Senhadji O., Marais S., Lanel C., Fatyeyeva K., (2021). Novel Poly(Vinylidene Fluoride)/Montmorillonite Polymer Inclusion Membrane: Application to Cr(VI) Extraction from Polluted Water. Membranes 11(9), 682. DOI:10.3390/membranes11090682
Sepúlveda R. A., Ortega M., Donoso N., Jara A., (2018). Intoxicación por ácido acetilsalicílico, fisiopatología y manejo. Revista médica de Chile 146 (11), 1309-1316. DOI: 10.4067/S0034-98872018001101309
Shirzad, M., & Karimi, M. (2020). Statistical analysis and optimal design of polymer inclusion membrane for water treatment by Co (II) removal. Desalination and Water Treatment. 182, 194-207
Ulewicz M., Kozlowski C., Walkowiak W., (2004). Removal of Zn(II), Cd(II) and Cu(II) ions by polymer inclusion membrane with side-armed diphosphaza-16-crown-6 ethers. Physicochemical Problems of Mineral Processing, 38(2004), 131-138.
Vázquez M., Romero V., Fontàs C., Anticó E., Benavente J., (2014). Polymer inclusion membranes (PIMs) with the ionic liquid (IL) Aliquat 336 as extractant: Effect of base polymer and IL concentration on their physical–chemical and elastic characteristics. Journal of Membrane Science, 455, 312-319. DOI:10.1016/j.memsci.2013.12.072
Vera R., Anticó E., Eguiazábal J.I., Aranburu N., Fontàs C., (2019). First Report on a Solvent-Free Preparation of Polymer Inclusion Membranes with an Ionic Liquid. Molecules 24(10), 1845. DOI:10.3390/molecules24101845
Vieira A. W., Molina G., Mageste A. B., Rodrigues G. D., Lemos L. R., (2019). Partitioning of salicylic and acetylsalicylic acids by aqueous two-phase systems: Mechanism aspects and optimization study. Journal of Molecular Liquids. 296, 111775. DOI: 10.1016/j.molliq.2019.111775.
Wang D., Liu J., Chen J., Liu O., Zeng H., (2020). New insights into the interfacial behavior and swelling of polymer inclusion membrane (PIM) during Zn (II) extraction process, Chemical Engineering Science 220, 115620. DOI:10.1016/j.ces.2020.115620.
Zante G., Boltoeva M., Masmoudi A., Barillon R., Trébouet D., (2021). Supported ionic liquid and polymer inclusion membranes for metal separation. Separation & Purification Reviews 51(1), 100–116. DOI:10.1080/15422119.2020.1846564
Zawierucha I., Nowik-Zajac A., Malina G., (2020). Selective Removal of As(V) Ions from Acid Mine Drainage Using Polymer Inclusion Membranes. Minerals, 10(10), 909. DOI:10.3390/min10100909
Zsabka P., Van Hecke K., Adriaensen L., Wilden A., Modolo G., Verwerft M., Cardinaels T., (2018). Solvent extraction of Am(III), Cm(III) and Ln(III) ions from simulated highly active raffinate solutions by TODGA diluted in Aliquat-336 nitrate ionic liquid. Solvent extraction and ion Exchange. 36(6), 519-541. DOI: 10.1080/07366299.2018.1545288
Zuo K., Wang K., DuChanois R.M., Fang O., Deemer E.M., Huang X., Xin R., Said I.A., He Z., Feng Y., Walker W.S., Lou J., Elimelech M., Huang X., Qilin L. (2021). Selective membranes in water and wastewater treatment: Role of advanced materials 50, 516-532. DOI:10.1016/j.mattod.2021.06.013
Derechos de autor 2024 Jessica Marcial-Gutiérrez, María Elena Páez-Hernández, Carlos Andrés Galán-Vidal, Israel S. Ibarra, Irma Pérez-Silva
Esta obra está bajo licencia internacional Creative Commons Reconocimiento-NoComercial-SinObrasDerivadas 4.0.