Fotocatálisis tipo Fenton con Mn (II) en agua residual.

Ivon Claudia Plata; Claudia Romo Gómez; César Camacho-López; Otilio Arturo Acevedo Sandoval; Cesar Abelardo González Ramírez; Fernando Salas Martinez

Autores/as

Ivon Claudia Plata Universidad Autónoma del Estado de Hidalgo https://orcid.org/0009-0008-0664-9632
Claudia Romo Gómez Universidad Autónoma del Estado de Hidalgo https://orcid.org/0000-0001-7826-4557
César Camacho-López Universidad Autónoma del Estado de Hidalgo https://orcid.org/0000-0002-7392-9967
Otilio Arturo Acevedo Sandoval Universidad Autónoma del Estado de Hidalgo https://orcid.org/0000-0003-0475-7003
Cesar Abelardo González Ramírez Universidad Autónoma del Estado de Hidalgo https://orcid.org/0000-0001-9407-4542
Fernando Salas Martinez Universidad Autónoma del Estado de Hidalgo https://orcid.org/0000-0002-5104-5167

Palabras clave:

degradación, foto-Fenton, Manganeso, Agua residual

Resumen

El proceso Foto-Fenton es una alternativa prometedora para la eliminación de contaminantes orgánicos en agua residual, no obstante, está limitado a un pH de trabajo de 3-4. Por ello, se han estudiado metales de transición como el Mn que no limiten el desempeño del proceso. El objetivo del presente trabajo consistió en evaluar el proceso foto-Fenton con Mn (II) para la degradación de contaminantes en agua residual. Se realizaron ensayos Mn (10 - 100 mg L^-1) y H₂O₂ (150 - 600 mg L^-1) con relaciones Fe/Mn de 0.2, 0.5, 0.7 y 1, y agua residual al 10, 20, 40, 60, 80 y 100 %. Se logró eliminar la mayor cantidad de contaminantes del agua residual en ensayos con 50 mg L^-1 de Mn²⁺ y 600 mg L^-1 de H₂O₂. En los ensayos con Fe/Mn igual a 0.7, se obtuvieron las mayores degradaciones de contaminantes. El ion Mn²⁺ actuó como co-catalizador en el sistema foto-Fenton, mejorando el mecanismo clásico con Fe²⁺.

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