Fabricación por molienda mecánica y análisis estructural de soluciones sólidas tipo Ba1-xInxTi1-x/4O3

Daniela Patricia Herrera Flores; Irma Mendoza Sanchez; Edna Dalila German Magaldi; Miguel Perez Labra; Martín Reyes Pérez

Autores/as

Daniela Patricia Herrera Flores Universidad Autónoma del Estado de Hidalgo https://orcid.org/0009-0000-5260-0188
Irma Mendoza Sanchez Universidad Autónoma del Estado de Hidalgo https://orcid.org/0009-0006-3426-9077
Edna Dalila German Magaldi Universidad Autónoma del Estado de Hidalgo https://orcid.org/0009-0005-4792-8097
Miguel Perez Labra Universidad Autónoma del Estado de Hidalgo https://orcid.org/0000-0001-9882-6932
Martín Reyes Pérez Universidad Autónoma del Estado de Hidalgo https://orcid.org/0000-0003-3843-2397

Palabras clave:

BaTiO3, In3+, Dopaje, Ferroelectricidad

Resumen

Se analizó sistemáticamente la evolución estructural de soluciones sólidas Ba_1-xIn_xTi_1-x/4O₃ (x = 0.0, 0.001, 0.03 y 0.05 In³⁺ wt. %). Los polvos precursores fueron sometidos a molienda mecánica por 6 horas empleando bola de zirconia y posteriormente fueron sinterizados a 1100 °C durante 5 horas a 4 °C/min. Los resultados obtenidos por DRX indicaron la fase BaTiO₃tetragonal ferroeléctrica en las muestras x = 0.0 y 0.001, mientras que para x = 0.03 y 0.05 se determinó una estructura cúbica. El análisis de la evolución estructural obtenida mediante refinamiento Rietveld indicó un incremento en los parámetros a y b así como una disminución en el parámetro c cuando el contenido de In³⁺ incrementó, indicando una disminución progresiva en la relación de tetragonalidad (c/a). El valor promedio del volumen de celda de 64.60 Å³ fue observado para todas las composiciones dopadas en comparación con la muestra de BaTiO₃ puro de 64.32 Å³. La densidad teórica alcanzó un valor máximo para la muestra con x = 0.001 de 6.213 g/cm³, disminuyendo en composiciones con mayor contenido de dopante.

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