Reconocimiento molecular aniónico
DOI:
https://doi.org/10.29057/icbi.v2i4.541Palabras clave:
reconocimiento molecular, anión, receptor neutroResumen
El diseño y síntesis de receptores para el reconocimiento molecular de aniones es un área de investigación importante, debido al papel fundamental que los aniones presentan en la naturaleza, así como en medicina, catálisis, ciencias ambientales, biología y química. En este trabajo se describen aspectos importantes a considerar para el diseño de moléculas receptoras de aniones y ejemplos de receptores sintéticos neutros y cargados positivamente.
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Busschaert, N., Wenzel, M., Light, M. E., Iglesias-Hernández, P., Pérez-Tomás, R., Gale, P. A. (2011) Structure-Activity Relationships in Tripodal Transmembrane Anion Transporters: The Effect of Fluorination. J. Am. Chem. Soc. 133, 14136-14148.
Gale, P. A. Caltagirone, C. (2014)Anion sensing by small molecules and molecular ensembles. Chem. Soc. Rev. En prensa, doi:10.1039/C4CS00179F.
Gimeno, N., Li, X., Durrant, J. R., Vilar, R. (2008) Cyanide Sensing with Organic Dyes: Studies in Solution and on Nanostructured Al2O3 Surfaces. Chem. Eur. J., 14, 3006-3012.
Lehn, J.-M. (1973) Design of organic complexing agents strategies towards properties. Struct. Bonding. 16, 1-69.
Lehn, J.-M. (1988). Supramolecular Chemistry-Scope and Perspectives, Molecules, Supermolecules, and Molecular Devices (Nobel Lecture). Angew. Chem. Int. Ed. Engl. 27(1), 89-112.
Li, A.-F., Wang, J.-H., Wang, F., Jiang, Y.-B. (2010) Anion complexation and sensing using modified urea and thiourea-based receptors. Chem. Soc. Rev. 39, 3729-3745.
Park, C. H., Simmons, H. E. (1968) Macrobicyclic Amines. III. Encapsulation of Halide Ions by in, in-1,(k +2)-Diazabicyclo[k,l,m]alkane-ammonium Ions. J. Am. Chem. Soc., 90 (9), 2431-2432.
Sessler, J. L., Gale, P. A., Cho, W.-S. (2006) Anion Receptor Chemistry, RSC Publishing.
Zhang, Y.-M., Ren, H.-X., Zhou, Y.-Q., Luo, R., Xu, W.-X., Wei, T-B. (2007) Studies on the Anion Recognition Properties of Synthesized Receptors III: A Novel Thiourea-Based Receptor Constructed by Benzo-15-Crown-5 for Sensing Anions in a Strong Polar Solvent. Turk. J. Chem., 31, 327-334.
Ariga, K., Kunitake, T. (2006) Supramolecular Chemistry-Fundamentals and Applications, Springer.
Baron, R., McCammon, J. A. (2013) Molecular Recognition and Ligand Association. Annu. Rev. Phys. Chem., 64, 151-175.
Beer, P. D., Gale, P. A. (2001) Anion Recognition and Sensing: The State of the Art and Future Perspective. Angew. Chem., Int. Ed. Engl., 40(3), 486–516.
Bowman-James, K., Bianchi, A., García-España, E. (2012) Anion Coordination Chemistry, Wiley-VCH.
Busschaert, N., Wenzel, M., Light, M. E., Iglesias-Hernández, P., Pérez-Tomás, R., Gale, P. A. (2011) Structure-Activity Relationships in Tripodal Transmembrane Anion Transporters: The Effect of Fluorination. J. Am. Chem. Soc. 133, 14136-14148.
Gale, P. A. Caltagirone, C. (2014)Anion sensing by small molecules and molecular ensembles. Chem. Soc. Rev. En prensa, doi:10.1039/C4CS00179F.
Gimeno, N., Li, X., Durrant, J. R., Vilar, R. (2008) Cyanide Sensing with Organic Dyes: Studies in Solution and on Nanostructured Al2O3 Surfaces. Chem. Eur. J., 14, 3006-3012.
Lehn, J.-M. (1973) Design of organic complexing agents strategies towards properties. Struct. Bonding. 16, 1-69.
Lehn, J.-M. (1988). Supramolecular Chemistry-Scope and Perspectives, Molecules, Supermolecules, and Molecular Devices (Nobel Lecture). Angew. Chem. Int. Ed. Engl. 27(1), 89-112.
Li, A.-F., Wang, J.-H., Wang, F., Jiang, Y.-B. (2010) Anion complexation and sensing using modified urea and thiourea-based receptors. Chem. Soc. Rev. 39, 3729-3745.
Park, C. H., Simmons, H. E. (1968) Macrobicyclic Amines. III. Encapsulation of Halide Ions by in, in-1,(k +2)-Diazabicyclo[k,l,m]alkane-ammonium Ions. J. Am. Chem. Soc., 90 (9), 2431-2432.
Sessler, J. L., Gale, P. A., Cho, W.-S. (2006) Anion Receptor Chemistry, RSC Publishing.
Zhang, Y.-M., Ren, H.-X., Zhou, Y.-Q., Luo, R., Xu, W.-X., Wei, T-B. (2007) Studies on the Anion Recognition Properties of Synthesized Receptors III: A Novel Thiourea-Based Receptor Constructed by Benzo-15-Crown-5 for Sensing Anions in a Strong Polar Solvent. Turk. J. Chem., 31, 327-334.
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Publicado
2015-01-05
Cómo citar
Cortés Hernández, M., López Ruiz, H., & Rojas Lima, S. (2015). Reconocimiento molecular aniónico. Pädi Boletín Científico De Ciencias Básicas E Ingenierías Del ICBI, 2(4). https://doi.org/10.29057/icbi.v2i4.541
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