Degradación de farmacéuticos y colorantes por foto-Fenton con luz solar

Jocelyn Ramírez-Moreno; Claudia Romo-Gómez; César Camacho-López; Otilio Arturo  Acevedo-Sandoval; José Belisario  Leyva-Morales; Cesar Abelardo  González-Ramírez

Jocelyn Ramírez-Moreno Universidad Autónoma del Estado de Hidalgo (UAEH) https://orcid.org/0009-0006-8089-4447
Claudia Romo-Gómez Universidad Autónoma del Estado de Hidalgo (UAEH) https://orcid.org/0000-0001-7826-4557
César Camacho-López Universidad Autónoma del Estado de Hidalgo (UAEH) https://orcid.org/0000-0002-7392-9967
Otilio Arturo Acevedo-Sandoval Universidad Autónoma del Estado de Hidalgo (UAEH) https://orcid.org/0000-0003-0475-7003
José Belisario Leyva-Morales Universidad Autónoma del Estado de Hidalgo (UAEH) https://orcid.org/0000-0001-6149-7506
Cesar Abelardo González-Ramírez Universidad Autónoma del Estado de Hidalgo (UAEH) https://orcid.org/0000-0001-9407-4542

Keywords: 17β-estradiol, ampicillin, Red 40,, Yellow 5, photo-Fenton

Abstract

17β-estradiol (E2), ampicillin (AMP), as well as the synthetic dyes Red 40 and Yellow 5, have been included in the group of emerging contaminants (ECs). These generate different environmental problems such as endocrine disruption in aquatic biota at trace concentrations. Due to their complex structure, they are difficult to degrade by conventional treatments. Fenton-type advanced oxidation processes (AOP) have shown promising results in the oxidation of organic compounds in short reaction times. In this work, a photo-Fenton process was evaluated with sunlight for the elimination of E2, AMP, Red 40 and Yellow 5 dyes in water with H₂O₂ as an oxidizing agent and FeSO₄·7H₂O as a catalyst. Oxidation efficiencies of E2, AMP, Red 40 and Yellow 5 greater than 70% were obtained and the degradation followed a first-order reaction model. Therefore, photo-Fenton oxidation processes are efficient in the oxidation of E2 and AMP, as well as the decolorization of red 40 and yellow 5.

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