Cobalt electrodeposition on a gold electrode from bitartrate based electrolytic baths

Keywords: electrodeposition, Cobalt, Gold, Bitartrate

Abstract

In the present work we carried out a voltammetric study of the cobalt electrodeposition process of cobalt onto a gold substrate from a bitartrate-based electrolyte bath with a composition of CoCl2 0.01 M + KC4H5O6 0.05 M. The results indicate that, from the system studied, cobalt can be electrodeposited in the potential range located between -0.5 to -0.9 V. The behaviour of the peak current vs. the scan rate1/2 suggests a diffusion controlled process, where the value of the diffusion coefficient is 8.2x10-8 cm2 s-1.

Downloads

Download data is not yet available.

References

Ando, M., Kobayashi, T., Iijima, S., y Harita, M.. (1997). Optical Recognition of CO and H2 by Use of Gas-sensitive Au–Co3O4 Composite Films. J. Mater. Chem, 7, 1779-1783.

Beaurepaire, J.L., Mény, C., Panissod, P. y Bucher, J.P. (1997). Phys. Rev. B, 56, R7120.

Bhuiyan, M.S., Taylor, B.J., Paranthaman, M., Thompson, J.R., y Sinclair, J.W., (2008), J. Mater. Sci. 43, 1644.

Carcia, P.F., Meinhaldt, A.D., Suna, A., (1985). “Perpendicular Magnetic Anisotropy in Pd/Co Thin Film Layered Structures”. Appl. Phys. Lett., 47, 178-180.

Carcia, P.F., (1988). “Perpendicular Magnetic Anisotropy in Pd/Co and Pt/Co Thin Film Layered Structures”. J. Appl. Phys, 63, 5066-5073.

C.W. Chen, J. Mater. Sci. 26, 1705 (1991).

Draaisma, H. J. G., De Jonge, F. y W. J. M., Den Broeder, J.A. (1987). “Magnetic Interface Anisotropy in Pd/Co and Pd/Fe Multilayers”. J. Magn. Mater, 66, 351-355.

García, E. M., Lins, V. F. C. y Matencio, T. (2013). Metallic and Oxide Electrodeposition, Chap 5 in: Modern Surface Engineering Treatments. M. Aliofkhazraei., Ed., IntechOpen., DOI: 10.5772/55684.

Georgescu, V., Mazur, V., y Cheloglu, O. (1996). Preparation and Magnetic Properties of Electrodeposited Co/Pt Multilayers. J. Magn. Magn. Mater, 156, 27-28.

Georgescu, V., Mazur, V., y Pushsashu, B. (1997). 16th General Conference of the Condensed Matter Division of the European Physical Society. Abstracts, Print Service, Leuven, in: K.U. Leuven, 118.

Gómez, E. y Valles, E. (2002) J. Appl. Electrochem. 32, 693.

Greaves, S.J., Grundy, P.J., y Pollard, R.J. (1993). Magnetic Properties of Cobalt Layers and Co/Pt Multilayers. J. Magn. Magn. Mater, 121, 528-531.

Hashimoto, S., y Ochiai, Y. (1990). Co/Pt and Co/Pd Multilayers as Magneto-optical Recording Materials. J. Magn. Magn. Mater, 88, 211-226.

Hernández, M., Álvarez-Romero, G. A., Rivera, M., González-Montiel, S., Rios-Reyes, C. H., y Mendoza-Huizar, L. H. (2021). Influence of bitartrate ion concentration in the copper electrodeposition onto a polycrystalline gold electrode. Croatica Chemica Acta, 94(1), 1–6. https://doi.org/10.5562/CCA3757

Hutchins, M.G., Wright, P.J., y Grebenik, P.D. (1987). “Comparison of Different Forms of Black Cobalt Selective Solar Absorber Surfaces”. Solar Energy Mater, 16, 113-131.

Jyoko, Y., Kashiwabara, S., y Hayashi, Y. (1996). Preparation and Characterization of Electrodeposited Pt/Co Multilayers. J. Magn. Magn. Mater, 156, 35.

Joo, O.S., Jung, K.D., Min, S.K., y Pathan, H.M. (Number: 2007-793883). Korea Inst. Sci. & Technology (Koad-C). Derwent Primary Accession, Patent Number: KR635302-B1, 07.

Krause, A. Uhlemann, M., Gebert, A., y Schultz, L. (2004). Electrochim. Acta, 49, 4127.

Krause, A., Uhlemann, M., Gebert, A., y Schultz, L. (2007). J. Solid State Electrochem, 11, 679.

Mendoza -Huizar, L., H., Robles, J., y Palomar-Pardavé, M. (2002). Nucleation and growth of cobalt onto different substrates. Journal of Electroanalytical Chemistry, 521(1-2), 95-106. https://doi.org/10.1016/s0022-0728(02)00659-9.

Nkeng, P., Koening, J., Gautier, J., Chartiey, P., y Poillerat, G. (1996). “Enhancement of Surface Areas of Co3O4 and NiCo2O4 Electrocatalysts Prepared by Spray Pyrolysis. J. Electroanal. Chem, 402, 81-89.

Okamoto, Y., Imanaka, T., y Teranishi, S. (1980). Surface Structure of CoO-MoO3/Al2O3 Catalysts Studied by X-ray Photoelectron Spectroscopy”. J. Cata, 65, 448-460.

Ramachandram, K., Oriakhi, C.O., Lerner, M.M., y Koch, V. R. (1996). “Intercalation Chemistry of Cobalt and Nickel Dioxides: A facile Route to New Compounds Containing Organocations”. Mater. Res. Bull, 31, 767-772.

Sato, N., (1988). “Crystallographic Structure and Magnetism of Co-Pd and Co-Pt Films with an Artificially Layered Structure. J. Appl. Phys., 64, 6424-6433.

Schmicler, W., (1996). Interfacial electrochemistry. Oxford University Press.

Weichel, S., y Møller, P.J. (1988). Annealing-induced Microfaceting of the CoO (100) Surface Investigated by LEED and STM”. Surf. Sci, 399, 219-224.

Szmaja, W., Kozlowski, W., Balcerski, J., Kowalczyk, P.J., Grobelny, J., Cichomski, M. (2010), J. Alloys Compd. 506, 526.

Szmaja, W., Kozłowski, W., Polanski, K., Balcerski, J., Cichomski, M.,bGrobelny, J., Zielinski, M., Miekos, E. (2012) Chem. Phys. Lett. 542, 117.

Yamaura, H., Tamaki, J., Moriya, K., Miura, N., y Yamazoe, N. (1997). Highly Selective CO Sensor Using Indium Oxide Doubly Promoted by Cobalt Oxide and Gold. J. Electrochem. Soc, 44, L159-L160.

Zangari, G. (2015). Electrodeposition of alloys and Compounds in the Era of Microelectronics and Energy Conversion Technology. Coatings, 5, 195-218 DOI: 10.3390/coatings5020195.

Zeper, W.B., Greidanus, F. J. A. M. y Carcia, P.F., 81989). “Evaporated Co/Pt Layered Structures for Magneto-Optical Recording. IEEE Trans. Magn., 25, 3764-3766.

Published
2021-12-12
How to Cite
Cruz-Martínez, M. I., Rivera-Hernández, M., Álvarez-Romero, G. A., Nieto-Velázquez, S., & Mendoza-Huizar, L. H. (2021). Cobalt electrodeposition on a gold electrode from bitartrate based electrolytic baths . Pädi Boletín Científico De Ciencias Básicas E Ingenierías Del ICBI, 9(Especial2), 145-148. https://doi.org/10.29057/icbi.v9iEspecial2.8011

Most read articles by the same author(s)