Evaluation of the Luminescence of Carbon Quantum Dots Synthetized Through the Hydrothermal Method from Triticum

  • Carlos Alfredo Zamora Valencia Universidad Autónoma del Estado de Hidalgo
  • María Isabel Reyes Valderrama Universidad Autónoma del Estado de Hidalgo
  • Alejandro de Jesús Herrera Carbajal Universidad Autónoma del Estado de Hidalgo
  • Eleazar Salinas Rodríguez Universidad Autónoma del Estado de Hidalgo
  • Ventura Rodriguez Lugo Universidad Autónoma del Estado de Hidalgo
Keywords: quantum dots, hydrothermal treatment, luminescence

Abstract

In the present work, the synthesis of carbon quantum dots from Wheat (Triticum) was carried out by the hydrothermal method, optimizing the synthesis conditions for the control of the emission and composition of the surface for its potential application as a biomarker. The carbon quantum dots obtained were characterized by luminescence spectroscopy techniques, obtaining a maximum excitation at 371 nm and a maximum emission at 442 nm emitting a blue-cyan color within the visible range that was verified by the system of Chromatic coordinates, electron transitions π-π * and n-π * are presented by UV-Vis spectroscopy, as well as the calculation of Egap with values ​​of 1.61 and 2.13 eV. Finally, FT-IR spectroscopy shows functional groups such as OH-, CH, CN, C = C, CO, C-OH, COC, COOH, C = C, which allows the formation of functionalized carbon quantum dots for manufacturing of biomarkers.

Downloads

Download data is not yet available.

References

Y. Mejias Sánchez, N. Cabrera Cruz, A. M. Toledo Fernández, and O. J. Duany Machado, “La nanotecnología y sus posibilidades de aplicación en el campo científico-tecnológico,” Rev. Cuba. Salud Publica, vol. 35, no. 3, pp. 1–9, 2009.

M. Quintili, “Nanociencia y Nanotecnología... un mundo pequeño,” Cuaderno, vol. 42, pp. 125–155, 2012.

M. Elisa et al., “Síntesis Y Caracterización De Nuevas Su Uso En Nanomedicina,” pp. 5–12, 2014.

A. I. S. Solís, “Síntesis y caracterización de puntos cuanticos de CdSe con aplicaciones en celdas fotovoltaicas con configuración FTO/TiO2/CdSe/ZnS,” p. 69, 2014.

J. L. Movilla Rosell, “Confinamiento nanoscópico en estructuras semiconductoras cero-dimensionales,” p. 342, 2007.

S. Y. Lim, W. Shen, and Z. Gao, “Carbon quantum dots and their applications,” Chem. Soc. Rev., vol. 44, no. 1, pp. 362–381, 2015.

B. O. Dabbousi et al., “(CdSe)ZnS Core−Shell Quantum Dots: Synthesis and Characterization of a Size Series of Highly Luminescent Nanocrystallites,” J. Phys. Chem. B, vol. 101, no. 46, pp. 9463–9475, 1997.

M. Algarra et al., “Carbon dots obtained using hydrothermal treatment of formaldehyde. Cell imaging in vitro,” Nanoscale, vol. 6, no. 15, pp. 9071–9077, 2014.

X. Niu, G. Liu, L. Li, Z. Fu, H. Xu, and F. Cui, “Green and economical synthesis of nitrogen-doped carbon dots from vegetables for sensing and imaging applications,” RSC Adv., vol. 5, no. 115, pp. 95223–95229, 2015.

M. Asha Jhonsi and S. Thulasi, “A novel fluorescent carbon dots derived from tamarind,” Chem. Phys. Lett., vol. 661, pp. 179–184, 2016.

X. Feng et al., “Easy synthesis of photoluminescent N-doped carbon dots from winter melon for bio-imaging,” RSC Adv., vol. 5, no. 40, pp. 31250–31254, 2015.

F. Du et al., “Economical and green synthesis of bagasse-derived fluorescent carbon dots for biomedical applications,” Nanotechnology, vol. 25, no. 31, 2014.

N. Wang, Y. Wang, T. Guo, T. Yang, M. Chen, and J. Wang, “Green preparation of carbon dots with papaya as carbon source for effective fluorescent sensing of Iron (III) and Escherichia coli,” Biosens. Bioelectron., vol. 85, pp. 68–75, 2016.

S. Zhao et al., “Green Synthesis of Bifunctional Fluorescent Carbon Dots from Garlic for Cellular Imaging and Free Radical Scavenging,” ACS Appl. Mater. Interfaces, vol. 7, no. 31, pp. 17054–17060, 2015.

A. Sachdev and P. Gopinath, “Green synthesis of multifunctional carbon dots from coriander leaves and their potential application as antioxidants, sensors and bioimaging agents,” Analyst, vol. 140, no. 12, pp. 4260–4269, 2015.

V. N. Mehta, S. Jha, and S. K. Kailasa, “One-pot green synthesis of carbon dots by using Saccharum officinarum juice for fluorescent imaging of bacteria (Escherichia coli) and yeast (Saccharomyces cerevisiae) cells,” Mater. Sci. Eng. C, vol. 38, no. 1, pp. 20–27, 2014.

Z. L. Wu et al., “One-pot hydrothermal synthesis of highly luminescent nitrogen-doped amphoteric carbon dots for bioimaging from bombyx mori silk – natural proteins,” no. 207890, 2017.

A. Prasannan and T. Imae, “One-pot synthesis of fluorescent carbon dots from orange waste peels,” Ind. Eng. Chem. Res., vol. 52, no. 44, pp. 15673–15678, 2013.

A. M. Alam, B. Y. Park, Z. K. Ghouri, M. Park, and H. Y. Kim, “Synthesis of carbon quantum dots from cabbage with down- and up-conversion photoluminescence properties: Excellent imaging agent for biomedical applications,” Green Chem., vol. 17, no. 7, pp. 3791–3797, 2015.

J. Wang, Y. H. Ng, Y.-F. Lim, and G. W. Ho, “Vegetable-extracted carbon dots and their nanocomposites for enhanced photocatalytic H 2 production,” RSC Adv., vol. 4, no. 83, pp. 44117–44123, 2014.

V. N. Mehta, S. Jha, R. K. Singhal, and S. K. Kailasa, “Preparation of multicolor emitting carbon dots for HeLa cell imaging,” New J. Chem., vol. 38, no. 12, pp. 6152–6160, 2014.

D. Wang, X. Wang, Y. Guo, W. Liu, and W. Qin, “Luminescent properties of milk carbon dots and their sulphur and nitrogen doped analogues,” RSC Adv., vol. 4, no. 93, pp. 51658–51665, 2014.

Y. Xu et al., “Green synthesis of fluorescent carbon quantum dots for detection of Hg2+,” Chinese J. Anal. Chem., vol. 42, no. 9, pp. 1252–1258, 2014.

L. Wang and H. S. Zhou, “Green synthesis of luminescent nitrogen-doped carbon dots from milk and its imaging application,” Anal. Chem., vol. 86, no. 18, pp. 8902–8905, 2014.

J. R. Bhamore, S. Jha, R. K. Singhal, T. J. Park, and S. K. Kailasa, “Facile green synthesis of carbon dots from Pyrus pyrifolia fruit for assaying of Al3+ion via chelation enhanced fluorescence mechanism,” J. Mol. Liq., vol. 264, no. 2017, pp. 9–16, 2018.

V. N. Mehta, S. Jha, H. Basu, R. K. Singhal, and S. K. Kailasa, “One-step hydrothermal approach to fabricate carbon dots from apple juice for imaging of mycobacterium and fungal cells,” Sensors Actuators, B Chem., vol. 213, pp. 434–443, 2015.

Z. N. Juárez, M. E. Bárcenas-Pozos, and L. R. Hernández, “El grano de trigo : características generales y algunas problemáticas y soluciones a su almacenamiento,” Temas Sel. Ing. Aliment., vol. 8, no. 1, pp. 79–92, 2014.

B. De and N. Karak, “A green and facile approach for the synthesis of water soluble fluorescent carbon dots from banana juice,” RSC Adv., vol. 3, no. 22, pp. 8286–8290, 2013.

H. Huang, Y. Xu, C.-J. Tang, J.-R. Chen, A.-J. Wang, and J.-J. Feng, “Facile and green synthesis of photoluminescent carbon nanoparticles for cellular imaging,” New J. Chem., vol. 38, no. 2, p. 784, 2014.

L. Wu et al., “A Green Synthesis of Carbon Nanoparticle from Honey for RealTime Photoacoustic Imaging,” Nano Res., vol. 6, no. 5, pp. 312–325, 2013.

S. Ullah, “Measurement of optical band gap of semiconductor materials,” 2015.

L. A. García Pérez, “Crecimiento y caracterización de películas delgadas de CdTe:Cu,” 2007.

J. Shen, Y. Zhu, X. Yang, and C. Li, “Graphene quantum dots: Emergent nanolights for bioimaging, sensors, catalysis and photovoltaic devices,” Chem. Commun., vol. 48, no. 31, pp. 3686–3699, 2012.

C. Jiang, H. Wu, X. Song, X. Ma, J. Wang, and M. Tan, “Presence of photoluminescent carbon dots in Nescafe®original instant coffee: Applications to bioimaging,” Talanta, vol. 127, pp. 68–74, 2014.

R. Bandi, B. R. Gangapuram, R. Dadigala, R. Eslavath, S. S. Singh, and V. Guttena, “Facile and green synthesis of fluorescent carbon dots from onion waste and their potential applications as sensor and multicolour imaging agents,” RSC Adv., vol. 6, no. 34, pp. 28633–28639, 2016.

X. Jia, J. Li, and E. Wang, “One-pot green synthesis of optically pH-sensitive carbon dots with upconversion luminescence,” Nanoscale, vol. 4, no. 18, pp. 5572–5575, 2012.

Published
2019-12-13
How to Cite
Zamora Valencia, C. A., Reyes Valderrama, M. I., Herrera Carbajal, A. de J., Salinas Rodríguez, E., & Rodriguez Lugo, V. (2019). Evaluation of the Luminescence of Carbon Quantum Dots Synthetized Through the Hydrothermal Method from Triticum. Pädi Boletín Científico De Ciencias Básicas E Ingenierías Del ICBI, 7(Especial-2), 19-22. https://doi.org/10.29057/icbi.v7iEspecial-2.4745

Most read articles by the same author(s)

1 2 > >>