Manganese (II) Extraction from Aqueous Solutions Using a Chelating Resin Loaded with Alizarin Red S
Abstract
Manganese is an essential micronutrient whose both excess and deficiency cause serious health problems. Determination of trace concentrations of manganese in environmental and food samples is difficult due to different factors, mainly to the low metal contents and to the complexity of the matrices. Therefore, sensitive techniques are necessary for determination of manganese. Some common techniques are time-consuming and expensive, but flame atomic absorption spectroscopy presents advantages such as low cost, operational facilities and good selectivity. However, a preconcentration step is required. The aim of this work was to incorporate a chelating agent (alizarin red S) on an anionic exchanger to improve the extraction of manganese (II) and its quantification by flame atomic absorption spectroscopy. The method was applied to the determination of manganese in synthetic solutions and in real samples (urban runoff and baby food).
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Barbosa, A.E., Fernandes, J.N., David, L.M. 2012. Key issues for sustainable urban stormwater management. Water research. 46(20), 6787-6798
Ciopec, M., Davidescu, C.M., Negrea, A., Grozav, I., Lupa, L., Negrea, P., Popa, A. 2012. Adsorption studies of Cr(III) ions from aqueous solutions by DEHPA impregnated onto Amberlite XAD7–Factorial design analysis. Chemical engineering research and design. 90(10), 1660-1670
da Silva, E.D.N., Leme, A.B.P., Cidade, M., Cadore, S. 2013. Evaluation of the bioaccessible fractions of Fe, Zn, Cu and Mn in baby foods. Talanta. 117, 184 188
Eldridge, R.J. 2000. Chelating ion exchange resins. Encyclopedia of separation science. 2271-2279
Fain, V.Y., Zaitsev, B.E., Ryabov, M.A. 2004a. Metal complexes with alizarin and alizarin red S: Electronic absorption spectra and structure of ligands. Russian journal of coordination chemistry. 30(5), 365-370
Fain, V.Y., Zaitsev, B.E., Ryabov, M.A. 2004b. Quantum-chemical and correlation study of ionization of alizarin. Russian journal of general chemistry. 74(10), 1558-1563
Ghosh, A., Jose, D.A., Kaushik, R. 2016. Anthraquinones as versatile colorimetric reagent for anions. Sensors and Actuators B: Chemical. 229, 545-560
Hosseini-Bandegharaei, A., Hosseini, M.S., Jalalabadi, Y., Nedaie, M., Sarwghadi, M., Taherian, A., Hosseini, E. 2013. A novel extractant-impregnated resin containing carminic acid for selective separation and pre-concentration of uranium (VI) and thorium (IV). International journal of environmental analytical chemistry. 93(1), 108-124
Korn, M.D.G.A., Santos Jr, A.D.F., Jaeger, H.V., Silva, N.M.S., Costa, A.C.S. 2004. Copper, zinc and manganese determination in saline samples employing FAAS after separation and preconcentration on amberlite XAD-7 and Dowex 1X-8 loaded with alizarin red S. Journal of the Brazilian Chemical Society. 15(2), 212-218
Naushad, M., Vasudevan, S., Sharma, G., Kumar, A., ALOthman, Z.A. 2016. Adsorption kinetics, isotherms, and thermodynamic studies for Hg2+ adsorption from aqueous medium using alizarin red-S-loaded amberlite IRA-400 resin. Desalination and water treatment. 57(39), 18551-18559
Nejati-Yazdinejad, M. 2006. Spectrophotometric determination of trace amount of copper (II) ion based on complexation with an anthraquinone derivative. Analytical sciences. 22(4), 617-619
O’Neal, S.L., Zheng, W. 2015. Manganese toxicity upon overexposure: a decade in review. Current environmental health reports. 2(3), 315-328
Ortiz-Hernández, J., Lucho-Constantino, C., Lizárraga-Mendiola, L., Beltrán-Hernández, R.I., Coronel-Olivares, C., Vázquez-Rodríguez, G. 2016. Quality of urban runoff in wet and dry seasons: a case study in a semi-arid zone. Environmental science and pollution research. 23(24), 25156-25168
Tavallali, H., Malekzadeh, H., Dadvar, F., Tabandeh, M., Haghshenas, M. 2017. Chemically functionalized γ-alumina
with alizarin red S for separation and determination of trace amounts of Pb(II) and Ag(I) ions by solid phase extraction–flame atomic absorption spectrometry in environmental and biological samples. Arabian journal of chemistry. 10, S2090-S2097
Viñas, P., Pardo-Martínez, M., Hernández-Córdoba, M. 2000. Determination of copper, cobalt, nickel, and manganese in baby food slurries using electrothermal atomic absorption spectrometry. Journal of agricultural and food chemistry. 48(12), 5789-5794
Yadav, L., Sanjay, S.S., Ankit, P., Chattopadhyaya, M.C. 2010. Simultaneous determination of stability constant and molar absorptivity coefficient of the charge-transfer complexes of metal–alizarin red S. Der pharma chemica. 2, 114-121